1-(4-pyridyloxy)carbonyl-1'-dodecylferrocene | 937163-50-3

• 英文名称: 1-(4-pyridyloxy)carbonyl-1'-dodecylferrocene
• 英文别名: (NC5H4)CO2(fc)C12H25
• CAS: 937163-50-3
• 化学式: C₂₈H₃₇FeNO₂
• 分子量: 475.454
• InChiKey: VVZCDPTXYTVRHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  十二羰基三钌 、 1-(4-pyridyloxy)carbonyl-1'-dodecylferrocene 、 苯甲酸 以 四氢呋喃 为溶剂， 以73%的产率得到[Ru2(CO)4(μ2-η2-benzoic acid-H)2(1-(4-pyridyloxy)carbonyl)-1'-dodecylferrocene)2]
  参考文献：
  名称：

  Dinuclear ruthenium sawhorse-type complexes containing carboxylato bridges and ferrocenyl substituents: Synthesis and electrochemistry

  摘要：

  The ferrocenyl-containing diruthenium complexes [Ru-2(CO)(4)(mu(2)-eta(2)-OOCFc)(2)L-2] (Fc=ferrocenyl, fc=ferrocen-1,1'-diyl; 1: L=NC5H4-COOC6H4-OC10H21, 2: L=NC5H4-COOC6H4-OC16H33, 3: L=NC5H4-OOC-fc-C12H25) and [Ru-2(CO)(4)(mu(2)-eta(2)- OOC6H5)(2)(NC5H4-OOC-fc-C12H25)(2)] (4) have been synthesized from Ru-3(CO)(12), ferrocene carboxylic or benzoic acid and the corresponding pyridine derivative. The synthesis of the new pyridine derivative NC5H4-OOC-fc-C12H25 used for the preparation of 3 and 4 is also reported. Complexes 1-4 posses a so-called sawhorse structure consisting of the Ru-2(CO)(4) backbone and two bridging carboxylato ligands, while the coordination sphere around the ruthenium atoms is completed by the pyridine-derived ligands bonded in the axial positions. The electrochemical behavior of 1-4 and their known analogues [Ru(CO)(4)(mu(2)-eta(2)-OOCFc)(2)L-2] (5: L = NC5H5, 6: L = P(C6H5)(3), 7: L = NC5H4-OOCFc) has been studied by voltammetry on rotating disc electrode and by cyclic voltammetry. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.10.020
• 作为产物：
  描述：

  4-羟基吡啶 、 1-carboxy-1'-dodecylferrocene 在 4-二甲氨基吡啶 、 4-吡咯烷基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 以64%的产率得到1-(4-pyridyloxy)carbonyl-1'-dodecylferrocene
  参考文献：
  名称：

  Dinuclear ruthenium sawhorse-type complexes containing carboxylato bridges and ferrocenyl substituents: Synthesis and electrochemistry

  摘要：

  The ferrocenyl-containing diruthenium complexes [Ru-2(CO)(4)(mu(2)-eta(2)-OOCFc)(2)L-2] (Fc=ferrocenyl, fc=ferrocen-1,1'-diyl; 1: L=NC5H4-COOC6H4-OC10H21, 2: L=NC5H4-COOC6H4-OC16H33, 3: L=NC5H4-OOC-fc-C12H25) and [Ru-2(CO)(4)(mu(2)-eta(2)- OOC6H5)(2)(NC5H4-OOC-fc-C12H25)(2)] (4) have been synthesized from Ru-3(CO)(12), ferrocene carboxylic or benzoic acid and the corresponding pyridine derivative. The synthesis of the new pyridine derivative NC5H4-OOC-fc-C12H25 used for the preparation of 3 and 4 is also reported. Complexes 1-4 posses a so-called sawhorse structure consisting of the Ru-2(CO)(4) backbone and two bridging carboxylato ligands, while the coordination sphere around the ruthenium atoms is completed by the pyridine-derived ligands bonded in the axial positions. The electrochemical behavior of 1-4 and their known analogues [Ru(CO)(4)(mu(2)-eta(2)-OOCFc)(2)L-2] (5: L = NC5H5, 6: L = P(C6H5)(3), 7: L = NC5H4-OOCFc) has been studied by voltammetry on rotating disc electrode and by cyclic voltammetry. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.10.020