| 185418-60-4

• CAS: 185418-60-4
• 化学式: C₄₂H₄₀Br₂NP₂RuS₂
• 分子量: 945.744
• InChiKey: FHSKMZKFKXGPKU-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [bis(triphenylphosphine) (methanol) ruthenium(III) tribromide] 、 sodium piperidinedithiocarbamate 以 苯 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  Synthesis, Characterisation and Antifungal Activity of Ru(III) Complexes with Heterocyclic Dithiocarbamates

  摘要：

  Several new hexa-coordinated ruthenium(III) complexes of the type [RuX(2)(EPh(3))(2)(LL(1))], (X = Cl or Br; E = P or As) [where LL(1) = morpholinedithiocarbamate (Morphdtc), piperidinedithiocarbamate (Pipdtc) and piperazinedithio-carbamate (Pzdtc) have been synthesised. In all these complexes the heterocyclic dithiocarbamates behave as a uninegative bidentate (SS) chelating ligand. It has been observed that the incoming ligand replaces a halide, a tertiary phosphine/arsine and methanol from the starting complexes. All the complexes have been characterised on the basis of analytical and spectroscopic data. The new complexes showed a reasonable amount of antifungal activities.

  DOI：

  10.1080/00945719608004400