[Cp(*)RuCl(CO)(PMe(i)Pr2)] | 659720-39-5

• 英文名称: [Cp(*)RuCl(CO)(PMe(i)Pr2)]
• CAS: 659720-39-5
• 化学式: C₁₈H₃₂ClOPRu
• 分子量: 431.948
• InChiKey: PKQKKGMIPLREFP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cp(*)RuCl(CO)(PMe(i)Pr2)] 、 tin(ll) chloride 以 二氯甲烷 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Preparation and Reactivity of Organometallic Complexes Bearing the Fragment “Cp*Ru(CO)(PR₃)” (PR₃ = PMeⁱPr₂, PEt₃):  Dinuclear Complexes [{Cp*Ru(CO)(PR₃)}₂(μ-Cl)]⁺ Containing Two Chiral Centers, η²-Alkene, and Other Mononuclear Complexes

  摘要：

  The reactions of [Cp*RuCl(CO)((PMePr2)-Pr-i)] (1) and [Cp*RuCl(CO)(PEt3)] (2) with NaBAr'(4) in fluorobenzene both under argon and under dinitrogen generate the binuclear compounds [{Cp*Ru(CO)((PMePr2)-Pr-i)}(2)(mu-Cl)] [BAr'(4)] (3) and [{Cp*Ru(CO)(PEt3)}(2)(mu-Cl)][BAr'(4)] (4), respectively, which were fully characterized. The crystal structure of compound 4 is reported, showing for the first time two chiral "Cp*Ru" fragments bonded through only one bridging chloride ligand. No dinitrogen complexes or 16-electron species could be isolated. Halide abstraction from 1 using dry acetone as solvent yields the compound [Cp*Ru(CO){eta(1)-OC-(CH3)(2)}((PMePr2)-Pr-i)][BAr'(4)] (5). A range of olefins react with [Cp*RuCl(CO)((PMePr2)-Pr-i)] and NaBAr'(4) furnishing the corresponding cationic eta(2)-alkene complexes [Cp*Ru(CO)(L)((PMePr2)-Pr-i)] [BAr'(4)] (L = C2H4, 6; H2C = CHPh, 7; and H2C = CHCOOCH3, 8), which are stable under argon atmosphere in solution. The crystal structure of compound 6 is also reported. Both 1 and 2 react with SnCl2 in CH2Cl2 to yield the insertion derivatives [Cp*Ru(CO)(SnCl3)(PR3)] (PR3 = (PMePr2)-Pr-i, 9; PEt3, 10), which have also been characterized.

  DOI：

  10.1021/om034186x
• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)] 、 一氧化碳 、 diisopropylmethylphosphine 在 Zn 作用下， 以 四氢呋喃 为溶剂， 以90%的产率得到[Cp(*)RuCl(CO)(PMe(i)Pr2)]
  参考文献：
  名称：

  Preparation and Reactivity of Organometallic Complexes Bearing the Fragment “Cp*Ru(CO)(PR₃)” (PR₃ = PMeⁱPr₂, PEt₃):  Dinuclear Complexes [{Cp*Ru(CO)(PR₃)}₂(μ-Cl)]⁺ Containing Two Chiral Centers, η²-Alkene, and Other Mononuclear Complexes

  摘要：

  The reactions of [Cp*RuCl(CO)((PMePr2)-Pr-i)] (1) and [Cp*RuCl(CO)(PEt3)] (2) with NaBAr'(4) in fluorobenzene both under argon and under dinitrogen generate the binuclear compounds [{Cp*Ru(CO)((PMePr2)-Pr-i)}(2)(mu-Cl)] [BAr'(4)] (3) and [{Cp*Ru(CO)(PEt3)}(2)(mu-Cl)][BAr'(4)] (4), respectively, which were fully characterized. The crystal structure of compound 4 is reported, showing for the first time two chiral "Cp*Ru" fragments bonded through only one bridging chloride ligand. No dinitrogen complexes or 16-electron species could be isolated. Halide abstraction from 1 using dry acetone as solvent yields the compound [Cp*Ru(CO){eta(1)-OC-(CH3)(2)}((PMePr2)-Pr-i)][BAr'(4)] (5). A range of olefins react with [Cp*RuCl(CO)((PMePr2)-Pr-i)] and NaBAr'(4) furnishing the corresponding cationic eta(2)-alkene complexes [Cp*Ru(CO)(L)((PMePr2)-Pr-i)] [BAr'(4)] (L = C2H4, 6; H2C = CHPh, 7; and H2C = CHCOOCH3, 8), which are stable under argon atmosphere in solution. The crystal structure of compound 6 is also reported. Both 1 and 2 react with SnCl2 in CH2Cl2 to yield the insertion derivatives [Cp*Ru(CO)(SnCl3)(PR3)] (PR3 = (PMePr2)-Pr-i, 9; PEt3, 10), which have also been characterized.

  DOI：

  10.1021/om034186x

文献信息

• Activation of alkynes by {[Cp∗Ru(CO)(PMeiPr2)]+}: X-ray crystal structures of and
  作者：Manuel Jiménez-Tenorio、M. Dolores Palacios、M. Carmen Puerta、Pedro Valerga

  DOI：10.1016/j.jorganchem.2004.05.029

  日期：2004.9

  The complex [Cp∗RuOCMe2}(CO)(PMeiPr2)][BAr4′](2,Ar4′=3,5-C6H3(CF3)2) reacts with HCCPh at −40 °C in CD2Cl2 furnishing the π-alkyne adduct [Cp∗Ru(η2-HCCPh)(CO)(PMeiPr2)][BAr4′] (3), which rearranges to the vinylidene complex [Cp∗RuCCHPh(CO)(PMeiPr2)][BAr4′] (4a) when the temperature is raised to 25 °C. [Cp∗RuCCHR(CO)(PMeiPr2)][BAr4′] (R = Ph 4a, tBu4b, H 4c) were obtained by reaction of [Cp∗RuCl(CO)(PMeiPr2)]

  复杂的[CP *茹OCMe2}（CO）（PMeiPr2）] [BAr4']（2，Ar 4中'= 3,5- C6H3（CF 3）2）在光盘与HCCPh发生反应在-40℃下2氯2家具π-炔烃加合物[CP ∗ Ru（η2-HCCPh）（CO）（PMeiPr2）] [BAr4'] （3），其重排为亚乙烯基配合物[CP ∗ RuCCHPh（CO）（PMeiPr2）] [BAr4'] （4a）当温度升高到25°C时 [CP ∗ RuCCHR（CO）（PMeiPr2）] [BAr4'] （R = Ph 4a，t Bu 4b，H 4c）是通过[CP ∗ RuCl（CO）（PMe i Pr 2）]的反应获得的（1）与NaBAr4'和炔烃在氟苯中。在亚乙烯基络合物中加水会生成二羰基[CP ∗ Ru（CO）2（PMeiPr2）] [BAr4'] （5），而去质子化会产生中性的σ-炔基络合物[CP ∗ Ru（CCR）（CO）（