[Rh(NBD)(μ-3-methyl-5-tert-butylpyrazolate)]2 | 177360-77-9

• 英文名称: [Rh(NBD)(μ-3-methyl-5-tert-butylpyrazolate)]2
• CAS: 177360-77-9
• 化学式: C₃₀H₄₂N₄Rh₂
• 分子量: 664.501
• InChiKey: FBLBLETWYGOORF-YBNOVESCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Rh(NBD)(μ-3-methyl-5-tert-butylpyrazolate)]2 、 一氧化碳 以 二氯甲烷 为溶剂， 以84%的产率得到[Rh(CO)2(μ-3-methyl-5-tert-butylpyrazolate)]2
  参考文献：
  名称：

  Symmetric and dissymetric pyrazolyl-bridged rhodium dimers. Two X-ray dirhodium structures with short metal-metal interactions

  摘要：

  The molecular structure of complexes [{Rh(mu-pz*)(NBD)}(2)] (1a-7a) and [{Rh(mu-pz*)(CO)(2)}(2)] (1b-7b) (pz*=pyrazolate, 3,5-dimethylpyrazolate, 3(5)tert-butylpyrazolate, 3-methyl-5-tert-butylpyrazolate, 3(5)-phenylpyrazolate, 3-methyl-5-phenylpyrazolate and 3(5)-p-methoxyphenylpyrazolate) has been studied by IR and H-1 and C-13 NMR spectroscopies. H-1 NMR variable temperature experiments were also carried out. We also report the crystalline structure of two complexes isolated as unique configurational isomers, [{Rh(mu-bupz)(NBD)}(2)]. CH2Cl2 . H2O (3a), and [{Rh(mu-mbupz)(NBD)}(2)]. CH2Cl2 (4a).

  DOI：

  10.1016/0022-328x(95)05942-i
• 作为产物：
  描述：

  [(norbornadiene)rhodium(I)chloride]2 、 3-叔丁基-5-甲基-1H-吡唑 在 KOH 作用下， 以 甲醇 为溶剂， 以76%的产率得到[Rh(NBD)(μ-3-methyl-5-tert-butylpyrazolate)]2
  参考文献：
  名称：

  Symmetric and dissymetric pyrazolyl-bridged rhodium dimers. Two X-ray dirhodium structures with short metal-metal interactions

  摘要：

  The molecular structure of complexes [{Rh(mu-pz*)(NBD)}(2)] (1a-7a) and [{Rh(mu-pz*)(CO)(2)}(2)] (1b-7b) (pz*=pyrazolate, 3,5-dimethylpyrazolate, 3(5)tert-butylpyrazolate, 3-methyl-5-tert-butylpyrazolate, 3(5)-phenylpyrazolate, 3-methyl-5-phenylpyrazolate and 3(5)-p-methoxyphenylpyrazolate) has been studied by IR and H-1 and C-13 NMR spectroscopies. H-1 NMR variable temperature experiments were also carried out. We also report the crystalline structure of two complexes isolated as unique configurational isomers, [{Rh(mu-bupz)(NBD)}(2)]. CH2Cl2 . H2O (3a), and [{Rh(mu-mbupz)(NBD)}(2)]. CH2Cl2 (4a).

  DOI：

  10.1016/0022-328x(95)05942-i