Fe(η5-C5H5)(η5-C5H4CH2OC3H6BO2C6H4) | 1392114-77-0

• 英文名称: Fe(η5-C5H5)(η5-C5H4CH2OC3H6BO2C6H4)
• CAS: 1392114-77-0
• 化学式: C₂₀H₂₁BFeO₃
• 分子量: 376.043
• InChiKey: ZOSHZLSQWICPSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (2-propenyloxy)methylferrocene 、 儿萘酚硼烷 以 四氢呋喃 为溶剂， 以76%的产率得到Fe(η5-C5H5)(η5-C5H4CH2OC3H6BO2C6H4)
  参考文献：
  名称：

  Catecholboryl-functionalized ferrocene based Lewis acid system: A selective probe for fluoride ion through multiple channels

  摘要：

  The design and synthesis of two new receptors, C20H19O3BFe and C20H21O3BFe and their anion sensing properties through multiple channels are reported. Both the receptors, having chelating boronic ester Lewis acidic centre as the sole binding site, selectively bind fluoride ion in micromolar concentration. The binding constant of C20H19O3BFe with the fluoride ion has been found to be quite high [K = 10(6) M-1], whereas it displays a negligible affinity towards other effective competitors, for example acetate and cyanide (K = 10 M-1) and no sensitivity towards other halide ions. Upon selective recognition of F- in acetonitrile, the redox potential of C20H19O3BFe shifted by Delta E = 200 mV and the fluorescence emission was quenched drastically. The considerable changes in their absorption spectra are accompanied by the appearance of a new low energy (LE) peak at 566 nm and by a strong colour change from yellow to deep green which allows the prospective for "naked eye" detection of F- anion. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.06.005