[gold(I)(PEt3)2]BF4 | 65583-72-4

• 英文名称: [gold(I)(PEt3)2]BF4
• CAS: 65583-72-4
• 化学式: BF₄*C₁₂H₃₀AuP₂
• 分子量: 520.089
• InChiKey: LQHLPVGSPZFTOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Au(PEt₃)₂]Cl 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以97%的产率得到[gold(I)(PEt3)2]BF4
  参考文献：
  名称：

  Chemistry of Polynuclear Cationic Gold(I) Thiolates of Formula [Au ₂ (S t Bu)(L ₂ )][BF ₄ ]

  摘要：

  AbstractThe reactivity of the gold(I) cationic complexes [Au2(StBu)(L2)][BF4] {L = PMe3, PEt3, PtBu3; L2 = dppe [dppe = 1,2‐bis(diphenylphosphanyl)ethane]} was studied. These complexes undergo cleavage of the Au–Au bonds by reaction with phosphanes to give quantitative yields of [Au(StBu)(L)n] and [Au(L)n][BF4] (n = 2 or 3) in the case of monodentate phosphanes, and [Au2(StBu)2(dppe)] and [Au(dppe)2][BF4] in the case of the dppe derivative. These compounds also react with [Au(StBu)(L)] and exchange the neutral moiety bonded to the [Au(L)]+ cation. In both cases some indication of the nature of the intermediates was reached by mass spectrometry (ESI) and NMR spectroscopy. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200800918