[Pd(η3-CH2C*NHp-tol)CH2)(PPh3)2]BF4 | 575450-45-2

• 英文名称: [Pd(η3-CH2C*NHp-tol)CH2)(PPh3)2]BF4
• CAS: 575450-45-2
• 化学式: BF₄*C₄₆H₄₂NP₂Pd
• 分子量: 864.018
• InChiKey: HNRUEFCHNCTNRQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  bis{(μ-hydroxy)bis(triphenylphosphine)palladium(II)} tetrafluoroborate 、 乙烷,三氯氟- 以 丙酮 为溶剂， 以75%的产率得到[Pd(η3-CH2C*NHp-tol)CH2)(PPh3)2]BF4
  参考文献：
  名称：

  Reaction chemistry of [Pd2(μ-OH)2L4]2+ with aryl amines.

  摘要：

  The reaction of [Pd-2(mu-OH)(2)(PPh3)(4)](BF4)(2) (1) with aromatic amines (aniline and p-toluidine) in dichloromethane yields the dinuclear complexes [Pd-2(mu-OH)(mu-NHAr)(PPh3)(4)](BF4)(2) (2) (Ar =Ph, p -tol). The same reaction in acetone gives the palladium(II) allyl complex, [Pd(eta(3)-CH2C(NHp-tol)CH2)(PPh3)(2)](BF4) (3). An attempt to prepare the PMe2Ph analog of I as the PF6- salt yielded instead [Pd(PMe2Ph)(2)(mu-PF2O2)](2)(PF6)(2) (7). The structures of 2 (Ar = p-tol), 3, and 7 have been determined by X-ray diffraction methods. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01278-1