chloro(2,2':6',2''-terpyridine)platinum(II) chloride dimethylsulfoxide solvate | 932382-78-0

• 英文名称: chloro(2,2':6',2''-terpyridine)platinum(II) chloride dimethylsulfoxide solvate
• CAS: 932382-78-0
• 化学式: C₂H₆OS*C₁₅H₁₁ClN₃Pt*Cl
• 分子量: 577.393
• InChiKey: YCZWNZRLJIWLNQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloro(2,2':6',2''-terpyridine)platinum(II) chloride 、 二甲基亚砜 以 二甲基亚砜 为溶剂， 生成 chloro(2,2':6',2''-terpyridine)platinum(II) chloride dimethylsulfoxide solvate
  参考文献：
  名称：

  Red and yellow solvates of chloro(2,2′:6′,2′′-terpyridine)platinum(II) chloride and Pt...Pt interactions

  摘要：

  Crystallization of chloro(2,2':6',2"-terpyridine)platinum(II) chloride from dimethyl sulfoxide yields a red polymorph, [PtCl(C15H11N3)]Cl center dot C2H6OS, (I), which exhibits stacking along the a axis through pairs of Pt center dot center dot center dot Pt(-x, -y, -z) interactions of 3.3155 (8) angstrom. The cations are further associated through close Pt center dot center dot center dot Pt(1 - x, -y, -z) distances of 3.4360 (8) angstrom. Recrystallization from water gives a merohedrally twinned yellow-orange dihydrate form, [PtCl(C15H11N3)]Cl center dot 2H(2)O, (II), with pairwise short Pt center dot center dot center dot Pt(1 - x, 2 - y, -z) contacts of 3.3903 (5) angstrom but no long-range stacking through the crystals. Interpair Pt center dot center dot center dot Pt(-x, 2 - y, -z) distances between cation pairs in the hydrate are 4.3269 (5) angstrom.

  DOI：

  10.1107/s010827010601924x