CuDB | 1364521-79-8

• 英文名称: CuDB
• 英文别名: [Cu(bis[2-(diphenylphosphino)phenyl]ether)(benzo[i]dipyrido[3,2-a:2',3'-c]phenazine)]BF4；(bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-dibenzo[a,c]triphenylene)copper(I) tetrafluoroborate
• CAS: 1364521-79-8
• 化学式: BF₄*C₅₈H₄₀CuN₄OP₂
• 分子量: 1021.28
• InChiKey: KRIPSEJHGIHBKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 benzo[i]dipyrido[3,2-a:2',3'-c]phenazine 、 双(2-二苯基磷苯基)醚 以 二氯甲烷 为溶剂， 生成 CuDB
  参考文献：
  名称：

  The improved efficiency of low molecular weight organic solar cells doped with a Cu(I) triplet material

  摘要：

  We developed a method to improve the performance of the copper phthalocyanine (CuPc)/fullerene (C-60) organic solar cells (OSCs) by doping CuPc with a long triplet lifetime material. By doping [Cu(bis[2-(diphenylphosphino)phenyl]ether)(benzo[i]dipyrido[3,2-a:2',3'-c]phenazine)]BF4 (CuDB) into CuPc, the enhanced short-circuit current density (J (SC)) of 6.213 mA/cm(2), open-circuit voltage (V (OC)) of 0.39 V and a peak power conversion efficiency (PCE) of 0.92% compared to 0.79% of the standard CuPc/C-60 OSCs are achieved under 1 sun AM 1.5 G illumination at an intensity of 100 mW/cm(2). The performance improvement is mainly attributed to the long triplet lifetime of CuDB (tau = 70.05 mu s) which leads to more effective exciton dissociation.

  DOI：

  10.1134/s0036024416080045