bis(4,4'-dinitro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenolato)dicopper(II) | 1145688-83-0

• 英文名称: bis(4,4'-dinitro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenolato)dicopper(II)
• CAS: 1145688-83-0
• 化学式: C₃₂H₂₄Cu₂N₈O₁₆
• 分子量: 903.679
• InChiKey: XHQZXPYZEFGXDD-UCZBHRPZSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,4'-dinitro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol 、 copper(II) acetate monohydrate 以 甲醇 、 丙酮 为溶剂， 以21.8%的产率得到bis(4,4'-dinitro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenolato)dicopper(II)
  参考文献：
  名称：

  Synthesis, crystal structure and spectroscopic behaviors of Co(II) and Cu(II) complexes with Salen-type bisoxime ligands

  摘要：

  Two Salen-type ligands (H(2)L(1), 4,4'-dichloro-2,2'-[(1,3-propylene)dioxybis(nitrilomethylidyne)]diphenol and H(2)L(2), 4,4'-dinitro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol) and their corresponding complexes ({[CoL(1)(MeOH)](2)(OAc)(2)Co} center dot 2MeOH and [CuL(2)](2)) have been synthesized and characterized by element analyses, (1)H NMR, FT-IR and UV-Vis spectra, TG-DTA and single crystal X-ray crystallography. Crystallographic data suggests the octahedral geometry for Co(II) complex and square-pyramidal geometry for Cu(II) complex. Furthermore, the. fluorescence behavior of Cu(II) complex in DMSO is discussed. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.028