(N,N'-propylenebis(3,5-di-tert-butyl(2-O)benzylidenimine)[BBr2]2 | 412014-86-9

• 英文名称: (N,N'-propylenebis(3,5-di-tert-butyl(2-O)benzylidenimine)[BBr2]2
• CAS: 412014-86-9
• 化学式: C₃₃H₄₈B₂Br₄N₂O₂
• 分子量: 845.994
• InChiKey: BUEFSZHZCSIAJY-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (N,N'-propylenebis(3,5-di-tert-butyl(2-O)benzylidenimine)[BBr2]2 、 三溴化硼 以 氘代氯仿 为溶剂， 生成 [(N,N'-propylenebis(3,5-di-tert-butyl(2-O)benzylidenimine)(BBr2)(BBr)]BBr4
  参考文献：
  名称：

  Catalytic Dealkylation of Phosphates with Binuclear Boron Compounds

  摘要：

  The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate.

  DOI：

  10.1021/ja017360m
• 作为产物：
  描述：

  (N,N'-propylenebis(3,5-di-tert-butyl(2-O)benzylidenimine)[B(OCH3)2]2 、 三溴化硼 以 正庚烷 、 甲苯 为溶剂， 以88%的产率得到(N,N'-propylenebis(3,5-di-tert-butyl(2-O)benzylidenimine)[BBr2]2
  参考文献：
  名称：

  Catalytic Dealkylation of Phosphates with Binuclear Boron Compounds

  摘要：

  The Salen(tBu) ligand and its derivatives were used to prepare binuclear boron complexes. These compounds have the formula, L(BBr2)2 (L = Salpen(tBu) and Salben(tBu)). These are formed from the reaction of the corresponding L[B(OMe)2]2 with BBr3. They represent a new type of binuclear boron compound. These compounds are active towards the dealkylation of many phosphates. They are also catalytically active with a stoichiometric amount of BBr3 to trimethylphosphate.

  DOI：

  10.1021/ja017360m