(CO)5W(bis[tris(trimethylsilyl)cyclopentadienyl]selane) | 639818-29-4

• 英文名称: (CO)5W(bis[tris(trimethylsilyl)cyclopentadienyl]selane)
• CAS: 639818-29-4
• 化学式: C₃₃H₅₈O₅SeSi₆W
• 分子量: 966.144
• InChiKey: SGMXJVFNNGKBLC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  六羰基钨 、 bis[tris(trimethylsilyl)cyclopentadienyl]selane 以 四氢呋喃 为溶剂， 以81.5%的产率得到(CO)5W(bis[tris(trimethylsilyl)cyclopentadienyl]selane)
  参考文献：
  名称：

  Synthesis and structure of free and complexed cyclopentadienyl selanes

  摘要：

  Substitution of cyclopentadiene by one to three Me(3)Si or t-Bu groups allows the formation of mono- and biscyclopentadienylmono-, di-, and triselanes. [(Me(3)Si)(3)C(5)H(2)](2)Se(2) is the first biscyclopentadienyldiselane characterized by single crystal X-ray diffraction. Crystal structures are also presented to show that such compounds can function as ligands via selenium or the cyclopentadienyl moieties. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00041-0