[(divinyl)(phenyl)phosphine] gold(I) chloride | 286384-11-0

• 英文名称: [(divinyl)(phenyl)phosphine] gold(I) chloride
• CAS: 286384-11-0
• 化学式: C₁₀H₁₁AuClP
• 分子量: 394.591
• InChiKey: VIPKGDYUHDGGPW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(divinyl)(phenyl)phosphine] gold(I) chloride 、 苯六硫酚 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Gold and platinum benzenehexathiolate complexes as large templates for the synthesis of 12-coordinate polyphosphine macrocycles

  摘要：

  A general strategy for the synthesis of large-ring, poly-donor macrocycles using multi-metal ion templates is outlined. This strategy is illustrated in the design and synthesis of the hexanuclear (divinyl)(phenyl)phosphine gold complex of benzenehexathiolate, {[(C2H3)(2)(Ph)P]Au}(6)(C6S6) (1), which undergoes macrocycle formation upon reaction with PhPH2 in the presence of AIBN (Scheme 1). NMR spectra (H-1 and P-31) and elemental analyses indicate that the resulting macrocycle is a 36-membered ring containing 12 phosphorus donors, six of which are coordinated to the six Au atoms in the Au-6(C6S6) core. A series of tri-platinum complexes, (P boolean AND P)Pt](3)(C6S6) (16-19), where (P boolean AND P) is a bidentate phosphine ligand, with three (P boolean AND P)Pt-II units coordinated to a C6S66- core, were also prepared as models for templated formation of other poly-phosphorus macrocycles. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00552-6
• 作为产物：
  描述：

  diethylsulfide gold(I) chloride * water 、 二乙烯基苯基膦 以 二氯甲烷 为溶剂， 以61%的产率得到[(divinyl)(phenyl)phosphine] gold(I) chloride
  参考文献：
  名称：

  Gold and platinum benzenehexathiolate complexes as large templates for the synthesis of 12-coordinate polyphosphine macrocycles

  摘要：

  A general strategy for the synthesis of large-ring, poly-donor macrocycles using multi-metal ion templates is outlined. This strategy is illustrated in the design and synthesis of the hexanuclear (divinyl)(phenyl)phosphine gold complex of benzenehexathiolate, {[(C2H3)(2)(Ph)P]Au}(6)(C6S6) (1), which undergoes macrocycle formation upon reaction with PhPH2 in the presence of AIBN (Scheme 1). NMR spectra (H-1 and P-31) and elemental analyses indicate that the resulting macrocycle is a 36-membered ring containing 12 phosphorus donors, six of which are coordinated to the six Au atoms in the Au-6(C6S6) core. A series of tri-platinum complexes, (P boolean AND P)Pt](3)(C6S6) (16-19), where (P boolean AND P) is a bidentate phosphine ligand, with three (P boolean AND P)Pt-II units coordinated to a C6S66- core, were also prepared as models for templated formation of other poly-phosphorus macrocycles. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00552-6