cis-[Ru(η3-Me3SiCC=C(H)SiMe3)(PMe3)4]BF4 | 1092096-08-6

• 英文名称: cis-[Ru(η3-Me3SiCC=C(H)SiMe3)(PMe3)4]BF4
• CAS: 1092096-08-6
• 化学式: BF₄*C₂₂H₅₅P₄RuSi₂
• 分子量: 687.619
• InChiKey: YLXLOYWBNPPCEY-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2,6-lutidinium tetrafluoroborate 、 cis-[Ru(η3-Me3SiCC=C(H)SiMe3)(PMe3)4]BF4 以 四氢呋喃 为溶剂， 以46%的产率得到trans-[Ru(CCH)(C=CH2)(PMe3)4]BF4
  参考文献：
  名称：

  Butenynyl and Vinylidene Complexes of Ruthenium

  摘要：

  Reaction of ruthenium bis-acetylide complexes with 2,6-lutidinium tetrafluoroborate gave butenynyl complexes cis-[Ru(eta(3)-RC CC=C(H)R)(PMe(3))(4)]BF(4) in moderate to good yields. The structure of cis[Ru(eta(3)-tBuC CC=C(H)tBu)(PMe(3))(4)]BF(4) was determined crystallographically. Attempts to prepare cis[Ru(eta(3)-MeC CC=C(H)Me)(PMe(3))(4)]BF(4) resulted in the formation of two isomers, which differ in the stereochemistry about the double bond. The reaction of two bis-acetylide complexes with methyl triflate afforded butenynyl-type complexes cis- [Ru(eta(3)-RC CC=C(Me)R)(PMe(3))(4)](+) (R = Me, Ph). The mixed acetylide-vinylidene complex trans-[Ru(C CSiMe(3))(C=CH(2))(PMe(3))(4)]PF(6) was prepared by the reaction of trans-Ru(C CSiMe(3))(2)(PMe(3))(4) with ammonium hexafluorophosphate. In addition, the crystal structure of trans-[Ru(C CH)(C=CH(2))(PMe(3))(4)]BF(4) is reported.

  DOI：

  10.1021/om800861g
• 作为产物：
  描述：

  2,6-lutidinium tetrafluoroborate 、 [Ru(CCSiMe3)2(PMe3)4] 以 四氢呋喃 为溶剂， 以69%的产率得到cis-[Ru(η3-Me3SiCC=C(H)SiMe3)(PMe3)4]BF4
  参考文献：
  名称：

  Butenynyl and Vinylidene Complexes of Ruthenium

  摘要：

  Reaction of ruthenium bis-acetylide complexes with 2,6-lutidinium tetrafluoroborate gave butenynyl complexes cis-[Ru(eta(3)-RC CC=C(H)R)(PMe(3))(4)]BF(4) in moderate to good yields. The structure of cis[Ru(eta(3)-tBuC CC=C(H)tBu)(PMe(3))(4)]BF(4) was determined crystallographically. Attempts to prepare cis[Ru(eta(3)-MeC CC=C(H)Me)(PMe(3))(4)]BF(4) resulted in the formation of two isomers, which differ in the stereochemistry about the double bond. The reaction of two bis-acetylide complexes with methyl triflate afforded butenynyl-type complexes cis- [Ru(eta(3)-RC CC=C(Me)R)(PMe(3))(4)](+) (R = Me, Ph). The mixed acetylide-vinylidene complex trans-[Ru(C CSiMe(3))(C=CH(2))(PMe(3))(4)]PF(6) was prepared by the reaction of trans-Ru(C CSiMe(3))(2)(PMe(3))(4) with ammonium hexafluorophosphate. In addition, the crystal structure of trans-[Ru(C CH)(C=CH(2))(PMe(3))(4)]BF(4) is reported.

  DOI：

  10.1021/om800861g