[Pd((4-CHO)C6H3C(H)=N(C6H11)-C2,N)Cl]2[μ-bis(diphenylphosphino)ethane] | 499135-71-6

• 英文名称: [Pd((4-CHO)C6H3C(H)=N(C6H11)-C2,N)Cl]2[μ-bis(diphenylphosphino)ethane]
• CAS: 499135-71-6
• 化学式: C₅₄H₅₆Cl₂N₂O₂P₂Pd₂
• 分子量: 1110.74
• InChiKey: XTHBDOOEIATKJJ-WCEJYEFASA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Pd((4-CHO)C6H3C(H)=N(C6H11)-C2,N)(μ-Cl)]2 、 1,2-双(二苯基膦)乙烷 以 丙酮 为溶剂， 以85%的产率得到[Pd((4-CHO)C6H3C(H)=N(C6H11)-C2,N)Cl]2[μ-bis(diphenylphosphino)ethane]
  参考文献：
  名称：

  Cyclopalladated compounds with bridging and chelating diphosphine ligands. Effect of ring size. Crystal and molecular structure of [{Pd[4-(COH)C6H3C(H)N(Cy)-C2,N](Cl)}2(μ-Ph2PCH2PPh2)]

  摘要：

  Treatment of the chloro-bridged dinuclear compound [{Pd[4-(COH)C6H3C(H)=N(Cy)-C2,N]}(mu-Cl)](2) (1) with tertiary diphosphines in 1:1 molar ratio gave [ Pd[4-(COH)C6H3C(H)=N(Cy)-C2,N](Cl)}(2)(mu-Ph2PRPPh2)] (R: CH2, 2; CH2CH2, 3; (CH2)(4) 4; (CH2)(6), 5; Fe(C5H4)(2), 6; trans-CH=CH, 7; Cequivalent toC, 8) with the diphosphine in a bridging mode. When the reaction was carried out in a 1:2 molar ratio in the presence of NH4PF6, the compounds [Pd{4-(COH)C6H3C(H)=NCy-C-2,N}(Ph2PRPPh2-P,P)][PF6] (R: CH2, 9; CH2CH2, 10; (CH2)(4), 11; (CH2)(6),12; Fe(C5H4)(2),13; 1,2-C6H4,14; cis-CH=CH, 15; NH, 16) with the diphosphine chelated to the palladium atom, were obtained. H-1 P-31-{H-1} and C-13-{H-1} NMR, IR and mass spectroscopic data are given. The crystal structure of compound 2 has been determined by X-ray crystallography. equivalent to(C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01170-1