bis[2-n-butyl-2-(piperidyldithiocarbamate)-1,3,2-oxathiastannolane] | 459431-38-0

• 英文名称: bis[2-n-butyl-2-(piperidyldithiocarbamate)-1,3,2-oxathiastannolane]
• CAS: 459431-38-0
• 化学式: C₂₄H₄₆N₂O₂S₆Sn₂
• 分子量: 824.457
• InChiKey: GEACLMXTEMSONR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  n-丁基氧酸酯 、 2-巯基乙醇 、 sodium piperidinedithiocarbamate 以 苯 为溶剂， 以31.9%的产率得到bis[2-n-butyl-2-(piperidyldithiocarbamate)-1,3,2-oxathiastannolane]
  参考文献：
  名称：

  Dimeric dithiocarbamates of stannolane. An example of the presence of secondary bonds in the formation of an inorganic ring. Molecular and crystal structure of 2-nbutyl-2-(dimethyldithiocarbamate)-1,3,2-oxathiastannolane and 2-nbutyl-2-(piperidyldithiocarbamate)-1,3,2-oxathiastannolane

  摘要：

  Two dithiocarbamate derivatives of stannolane, 2-(n)butyl-2-(dimethyldithiocarbamate)-1,3,2-oxathiastannolane and 2-(n)butyl-2-(piperidyldithiocarbamate)-1,3,2-oxathiastannolane have been obtained and full characterized. The X-ray single crystal diffraction studies show the presence of a dimer arrangement, through the formation of an inorganic ring. The bond lengths between the tin and all the S and O atoms are in the middle of covalent and secondary bonds, with a remarkable preference toward oxygen atoms. Both oxathiastannolane units present in solid state an equilibrium between conformations, while the arrangement of the three fused rings (oxathiastannolane-distannoxane-oxathiastannolane) is almost planar. (C) 2002 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0022-328x(02)01373-6