| 1609562-54-0

• CAS: 1609562-54-0
• 化学式: C₂₃H₂₅B₂F₄N₅
• 分子量: 469.101
• InChiKey: JUAIAIBJXHFUNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,2-bis((3,5-dimethyl-1H-pyrrol-2-yl)methylene)hydrazine 在 哌啶 、 对甲苯磺酸 、 三乙胺 作用下， 以 甲苯 为溶剂， 反应 12.17h， 生成
  参考文献：
  名称：

  Highly Fluorescent BF₂ Complexes of Hydrazine–Schiff Base Linked Bispyrrole

  摘要：

  A series of BF2 complexes of hydrazine-Schiff base linked bispyrrole have been prepared from a simple two-step reaction from commercially available substances and are highly fluorescent in solution, film, and solid states with larger Stokes shift and excellent photostabilities comparable or even super to those of their BODIPY analogues. These resultant fluorescent dyes are highly susceptible to the postfunctionalization, as demonstrated in this work via the Knoevenagel condensation to introducing functionalities or tether groups to the chromophore.

  DOI：

  10.1021/ol501162f

文献信息

• Synthesis of mono-(p-dimethylamino)styryl-containing BOPHY dye for a turn-on pH sensor
  作者：Xin-Dong Jiang、Yajun Su、Shuai Yue、Chen Li、Haifeng Yu、Han Zhang、Chang-Liang Sun、Lin-Jiu Xiao

  DOI：10.1039/c4ra15914d

  日期：——

  Mono-substitutional BOPHY 3a with a (p-dimethylamino)styryl group in the α-position was confirmed to be synthesized by the Knoevenagel-type condensation. Dimethylamino-containing BOPHY 3a can be used as a pH probe.

  单取代的BOPHY 3a，其α位点带有（p-二甲氨基）苯乙烯基团，已经被证实通过Knoevenagel型缩合反应合成。含有二甲氨基的BOPHY 3a可以用作pH探针。