trans-Rh(P(C6H11)3)2Cl(CNPh) | 162024-39-7

• 英文名称: trans-Rh(P(C6H11)3)2Cl(CNPh)
• CAS: 162024-39-7
• 化学式: C₄₃H₇₁ClNP₂Rh
• 分子量: 802.349
• InChiKey: XAGNERGGJLWLDJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  RhCl(tricyclohexylphosphine)2 、 N-phenyl-P-(2,4,6-tri-t-butylphenyl)iminomethylenephosphine 以 四氢呋喃 为溶剂， 以73%的产率得到trans-Rh(P(C6H11)3)2Cl(CNPh)
  参考文献：
  名称：

  Rhodium-Mediated Stoichiometric P:C Bond Cleavage and Catalytic Isomerization in Phosphacumulenes

  摘要：

  Reaction of Rh(PCy(3))(2)Cl (4a, Cy = cyclo-C6H11 with the phosphacumulenes Mes*P=C=X (X = O (1) X = NPh (2); Mes* = 2,4,6-(t-Bu)(3)C6H2) results in P=C bond cleavage to form [2,4-(t-Bu)(2)C6H2(6-CMe(2)CH(2)PH)](5) and trans-Rh(PCy(3))(2)Cl(CX) (6, X = O; 7,X = NPh), respectively. In contrast, 4a and related Rh(I) PPh(3) complexes are catalyst precursors for the rearrangement of Mes*P=C=CPh(2) 13) to its isomer [2,4-(t-Bu)(2)C6H2(6-CMe(2)CH(2)PCH=CPh(2))] (8); the intermediate [Rh(PCy(3))[eta(2)(P,C)-Mes*P=C=CPh(2)]Cl](n) (9a), which is itself an active catalyst for the isomerization, was isolated and characterized spectroscopically.

  DOI：

  10.1021/om00001a007