(DIOP)RuCl2(ethylenediamine) | 853412-11-0

• 英文名称: (DIOP)RuCl2(ethylenediamine)
• CAS: 853412-11-0
• 化学式: C₃₃H₄₀Cl₂N₂O₂P₂Ru
• 分子量: 730.616
• InChiKey: IBFHCHHTGCWDKB-YNNDYUHXSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuCl2(benzene)]2 、 4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane 、 乙二胺 以 N,N-二甲基甲酰胺 为溶剂， 以79%的产率得到(DIOP)RuCl2(ethylenediamine)
  参考文献：
  名称：

  Acceptorless, Neat, Ruthenium-Catalyzed Dehydrogenative Cyclization of Diols to Lactones

  摘要：

  We report the dehydrogenation of 1,4-butanediol to γ-butyrolactone catalyzed by soluble ruthenium complexes without solvent or a hydrogen acceptor. An alkylphosphine version of ruthenium bis-phosphine diamine catalysts has been prepared and was found to be the longest-lived catalyst for the conversion of 1,4-butanediol to γ-butyrolactone. The catalytic production of γ-butyrolactone from 1,4-butandiol with this catalyst is simple to conduct, environmentally friendly, and highly efficient.

  DOI：

  10.1021/om048983m