| 157620-38-7

• CAS: 157620-38-7
• 化学式: C₄₉H₄₄OP₂RuS
• 分子量: 843.971
• InChiKey: UFHGTCBIRYBJRY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  lithium aluminium deuteride 、 cyclopenta-1,3-diene;1,3-dimethylnaphtho[2,1-c]chromene-6-thione;diphenylphosphanylmethyl(diphenyl)phosphane;ruthenium(2+);tetrafluoroborate 以 四氢呋喃 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis and ring-opening reactions of cationic ruthenium biaryl thionolactone complexes

  摘要：

  The preparations of novel thionolactone-bridged configuratively labile biaryls and their [Cp(R3P)2Ru]+-complexes are described. The dynamics of helimerization of these complexes and their reactivity towards nucleophiles have been investigated. Hydride transfer reagents lead to a cleavage of the thionolactone bridge to give the corresponding thiolate complexes, apparently via intermediate exothiolactolate ruthenium complexes. A similar lactolate analog is formed upon addition of a mild S-nucleophile.

  DOI：

  10.1016/0022-328x(94)80213-0