](Fp)Ph2PCCPPh2][BF4] | 172952-38-4

• 英文名称: ](Fp)Ph2PCCPPh2][BF4]
• CAS: 172952-38-4
• 化学式: BF₄*C₃₃H₂₅FeO₂P₂
• 分子量: 658.159
• InChiKey: HMJWVMAEBOOSOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ](Fp)Ph2PCCPPh2][BF4] 、 [PPh4][HFe3(CO)9(μ3-η(2)-C=CH2)] 以 二氯甲烷 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Synthesis of a Zwitterionic P-Coordinated Complex with Bis(diphenylphosphino)acetylene

  摘要：

  New cationic, [(Fp)Ph(2)PC=CPPh(2)(F-p)](2+) (1) and [(Fp)Ph(2)PC=CPPh(2)](+) (2), and anionic, [Fe-3(CO)(9)(mu 3-CCH3)(Ph(2)PC= CPPh(2))](-) (3) and [{Fe-3(CO)9(mu(3)-CCH3)}2(Ph(2)PC=CPPh(2))](2-) (4), P-coordinate complexes with bis(diphenylphosphino)acetylene have been prepared. The zwitterionic P-coordinated iron complex [{Fe-3(CO)(9)(mu 3-CCH3)}Ph(2)PC=CPPh(2)(Fp)] (5) has been synthesized in two different ways and characterized by X-ray crystallography.

  DOI：

  10.1021/om950507w
• 作为产物：
  描述：

  cyclopentadienyl iron(II) dicarbonyl dimer 、 ferrocenium(III) tetrafluoroborate 、 双(二苯基磷)乙炔 以 二氯甲烷 为溶剂， 以79%的产率得到](Fp)Ph2PCCPPh2][BF4]
  参考文献：
  名称：

  Synthesis of a Zwitterionic P-Coordinated Complex with Bis(diphenylphosphino)acetylene

  摘要：

  New cationic, [(Fp)Ph(2)PC=CPPh(2)(F-p)](2+) (1) and [(Fp)Ph(2)PC=CPPh(2)](+) (2), and anionic, [Fe-3(CO)(9)(mu 3-CCH3)(Ph(2)PC= CPPh(2))](-) (3) and [{Fe-3(CO)9(mu(3)-CCH3)}2(Ph(2)PC=CPPh(2))](2-) (4), P-coordinate complexes with bis(diphenylphosphino)acetylene have been prepared. The zwitterionic P-coordinated iron complex [{Fe-3(CO)(9)(mu 3-CCH3)}Ph(2)PC=CPPh(2)(Fp)] (5) has been synthesized in two different ways and characterized by X-ray crystallography.

  DOI：

  10.1021/om950507w

文献信息

• Cationic molybdenum complexes with P-coordinated (diphenylphosphino)alkynes
  作者：Elmostafa Louattani、Joan Suades

  DOI：10.1016/s0022-328x(00)00256-4

  日期：2000.6

  New cationic P-coordinated (diphenylphosphino)alkyne complexes with molybdenum [(Mp)Ph2PCCR][BF4] R=H, Me, tBu, Ph, Tol; Mp=(C5H5)Mo(CO)3} have been prepared from reaction between a (diphenylphosphino)alkyne Ph2PCCR and the dinuclear complex [(C5H5)Mo(CO)3]2, with Ag(I) as oxidant. The bis(diphenyphosphosphino)acetylene Ph2PCCPPh2 led to the following homo- and heteronuclear metal complexes by the

  新的阳离子P-协调（二苯基膦基）炔复合物与钼[（MP）PH 2 PCCR] [BF 4 ] R = H，Me中，吨卜，PH，托尔; 熔点=（C 5 H ^ 5）的Mo（CO）3 }已从（二苯基膦基）炔博士之间反应而制备2 PCCR和双核配合物[（C 5 H ^ 5）的Mo（CO）3 ] 2，与Ag（I）作为氧化剂。双（diphenyphosphosphino）乙炔博士2 PCCPPh 2通过相同的方法导致了以下的均聚物和异核金属配合物：[（MP）PH 2 PCCPPh 2 ] [BF 4]，[（MP）PH 2 PCCPPh 2（MP）] [BF 4 ] 2和[（MP）PH 2 PCCPPh 2（FP）] [BF 4 ] 2 Fp的=（C 5 H ^ 5） Fe（CO）2 }。所述P-协调钼络合物的反应〔（MP）PH 2 PCCR] [BF 4 ]，在室温下八羰基二钴，得到阳离子杂金属配合物[（MP）PH