2-[1-(2,6-(diisopropylphenyl)imino)ethyl]-6-[1-(2,6-(diisopropylphenyl)imino)-4-pentenyl]pyridyliron(II) chloride | 395642-04-3

• 英文名称: 2-[1-(2,6-(diisopropylphenyl)imino)ethyl]-6-[1-(2,6-(diisopropylphenyl)imino)-4-pentenyl]pyridyliron(II) chloride
• CAS: 395642-04-3
• 化学式: C₃₆H₄₇Cl₂FeN₃
• 分子量: 648.542
• InChiKey: TYJOMYUZBCTXKB-PDUVANTKSA-L

反应信息

• 作为产物：
  描述：

  iron(II) chloride tetrahydrate 、 2-[1-(2,6-(diisopropylphenyl)imino)ethyl]-6-[1-(2,6-(diisopropylphenyl)imino)-4-pentenyl]pyridine 以 四氢呋喃 为溶剂， 以83%的产率得到2-[1-(2,6-(diisopropylphenyl)imino)ethyl]-6-[1-(2,6-(diisopropylphenyl)imino)-4-pentenyl]pyridyliron(II) chloride
  参考文献：
  名称：

  Immobilization of Bis(imino)pyridyliron(II) Complexes on Silica

  摘要：

  The well-known catalyst precursor 2,6-bis[1-((2,6-diisopropylphenyl)imino)ethyl]pyridine (1) is functionalized by various alkenyl groups to yield the corresponding alkenyl-functionalized 2,6-bis[1-((2,6-diisopropylphenyl)imino)ethyl]pyridine ligand. Reaction of these novel functionalized bis(imino)pyridyl ligands with iron(II) chloride results in the formation of precatalysts 5-7, which possess different spacer moieties. The possibility of self-immobilization has been investigated with respect to the chain length of the alkenyl moiety. Additionally, experiments to heterogenize these functionalized iron(II) complexes on modified silica via hydrosilation are presented (8-10). The immobilization has been studied by IR, and the resulting polymers have been characterized by GPC and static light scattering.

  DOI：

  10.1021/om000939t