[bis-azido-(α-naphthyl-(2-pyridylmethylene)amine) zinc(II)]2 | 908001-67-2

• 英文名称: [bis-azido-(α-naphthyl-(2-pyridylmethylene)amine) zinc(II)]2
• CAS: 908001-67-2
• 化学式: C₃₂H₂₄N₁₆Zn₂
• 分子量: 763.43
• InChiKey: UKDJBXOXABBSMY-YLMUJXHPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc(II) acetate dihydrate 、 (2-pyridyl)methylene(α-naphthyl)amine 、 sodium azide 以 甲醇 为溶剂， 以68%的产率得到[bis-azido-(α-naphthyl-(2-pyridylmethylene)amine) zinc(II)]2
  参考文献：
  名称：

  Zn(II)-azide complexes of diimine and azoimine functions: Synthesis, spectra and X-ray structures

  摘要：

  Two new series of Zn(II) complexes of alpha/beta-naphthyl-(2-pyridylmethylene)amine and 1-alkyl-2-(naphthyl-alpha/beta-azo)imidazoles with N-3(-) as a counter ion are described in this article. The single crystal X-ray structure of [Zn(beta-naphthyl-(2-pyridylmethylene)amine)(N-3)(2)](2) has revealed an end-on azido bridged dimer while [Zn(1-ethyl-2-(naphthyl-beta-azo)imidazole)(2)(N-3)(2)] is a monomer. The complexes are spectroscopically characterized. Examination of luminescence properties of the complexes suggests that the Schiff bases are emissive and the naphthylazo compounds are non-emissive. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.01.033