[RuCl(pyridine)4(acetone)](1+) | 1097623-86-3

• 英文名称: [RuCl(pyridine)4(acetone)](1+)
• 英文别名: [RuCl(pyridine)₄(acetone)](1+)；[RuCl(py)₄(acetone)](1+)
• CAS: 1097623-86-3
• 化学式: C₂₃H₂₆ClN₄ORu
• 分子量: 511.009
• InChiKey: XWNZSABVBDCQBD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 trans-[RuII(4-methoxypyridine)4(cyanate)2] 、 [RuCl(pyridine)4(acetone)](1+) 以 甲醇 、 丙酮 、 水 为溶剂， 反应 1.0h， 以98 mg的产率得到trans-[(NC)Ru(4-methoxypyridine)₄(μ-CN)Ru(pyridine)₄Cl]PF₆
  参考文献：
  名称：

  Communication between Remote Moieties in Linear Ru–Ru–Ru Trimetallic Cyanide-Bridged Complexes

  摘要：

  In this article, we report the structural, spectroscopic, and electrochemical properties of the cyanide-bridged complex salts trans-[(NC)Ru-II(L)(4)(mu-CN)Ru-II(py)(4)Cl]PF6 and trans-[Ru-II(L)(4){(mu-CN)-Ru-II(py)(4)Cl}(2)](PF6)(2) (L = pyridine or 4-methoxypyridine). The mixed-valence forms of these compounds show a variety of metal-to-metal charge-transfer bands, including one arising from charge transfer between the remote ruthenium units. The latter is more intense when L = 4-methoxypyridine and points to the role of the bridging ruthenium unit in promoting mixing between the d pi orbitals of the terminal fragments.

  DOI：

  10.1021/ic302173g
• 作为产物：
  描述：

  trans-chloro(nitrosyl)tetra(pyridine)ruthenium hexafluorophosphate 、 丙酮 在 sodium azide 作用下， 以 丙酮 为溶剂， 反应 1.0h， 生成 [RuCl(pyridine)4(acetone)](1+)
  参考文献：
  名称：

  Communication between Remote Moieties in Linear Ru–Ru–Ru Trimetallic Cyanide-Bridged Complexes

  摘要：

  In this article, we report the structural, spectroscopic, and electrochemical properties of the cyanide-bridged complex salts trans-[(NC)Ru-II(L)(4)(mu-CN)Ru-II(py)(4)Cl]PF6 and trans-[Ru-II(L)(4){(mu-CN)-Ru-II(py)(4)Cl}(2)](PF6)(2) (L = pyridine or 4-methoxypyridine). The mixed-valence forms of these compounds show a variety of metal-to-metal charge-transfer bands, including one arising from charge transfer between the remote ruthenium units. The latter is more intense when L = 4-methoxypyridine and points to the role of the bridging ruthenium unit in promoting mixing between the d pi orbitals of the terminal fragments.

  DOI：

  10.1021/ic302173g