chloro[2,3,12,13-tetrakis(trifluoromethyl)-5,10,15,20-tetraphenylporphyrinato]iron(III) | 561299-05-6

• 英文名称: chloro[2,3,12,13-tetrakis(trifluoromethyl)-5,10,15,20-tetraphenylporphyrinato]iron(III)
• CAS: 561299-05-6
• 化学式: C₄₈H₂₄ClF₁₂FeN₄
• 分子量: 976.026
• InChiKey: UYLDMBKVYPQGJV-XGGNIORYSA-M

反应信息

• 作为产物：
  描述：

  iron(II) chloride 、 5,10,15,20-tetraphenyl-2,3,12,13-tetrakis(trifluoromethyl)porphyrin 在 lithium hexamethyldisilazane 作用下， 以 四氢呋喃 为溶剂， 以62%的产率得到chloro[2,3,12,13-tetrakis(trifluoromethyl)-5,10,15,20-tetraphenylporphyrinato]iron(III)
  参考文献：
  名称：

  Synthesis of the hemin of β-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin and its evaluation as a P-450 mimic

  摘要：

  The hemin of beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin has been synthesized. Conventional methods for iron insertion failed; iron in low oxidation states (0 or II) brought about reduction of the macrocycle and Fe(III) failed to insert. Thus, insertion of iron into the macrocycle required the formation of the lithium complex, from lithium bis(trimethylsilyl)amide, followed by ferrous chloride. The novel hemin was tested as a catalyst for oxidations of cyclohexane and cyclohexene using iodosylbenzene as an oxidant and was found to be ineffective. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01389-0