1.2-(SNiS(P(C6H5)3)2)-1.2-C2B10H10 | 23868-64-6

• 英文名称: 1.2-(SNiS(P(C6H5)3)2)-1.2-C2B10H10
• CAS: 23868-64-6
• 化学式: C₃₈H₄₀B₁₀NiP₂S₂
• 分子量: 789.615
• InChiKey: SZLQUYXVFZBCJQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1.2-(SNiS(P(C6H5)3)2)-1.2-C2B10H10 、 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands

  摘要：

  Three mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands were synthesized and characterized by X-ray crystallography. The reactions of Ni(COD)(2)(COD=1,5-octadiene) with [(THF)(3)LiE2)C2B10H10Li(THF)](2) (E = S, Se) in THF in the presence of air in different ratios afforded the mono- and dinuclear nickel complexes of formulae Li(THF)(4)](2)[Ni(E2C2B10H10)(2)] (E=S, la; E=Se, 1b) and [Li(THF)(4)](2)[Ni-2(E(2)CZB(10)H(10))(3)] (E=S, 2a; E=Se, 2b). In 2a, two nickel atoms are connected by one chalcogen (eta(1),eta(2)-S2C2B10H10) bridging ligand with strong metal-metal interaction. Complex of formula (PPh3)(2)Ni(S2C2B10H10).0.5THF (3a) was also obtained from the reaction of (PPh3)(2)NiCl2 and [(THF)(3)LiS2C2B10H10Li(THF)](2). (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.05.001
• 作为产物：
  描述：

  bis(triphenylphosphine)nickel(II) chloride 、 以 四氢呋喃 为溶剂， 以80%的产率得到1.2-(SNiS(P(C6H5)3)2)-1.2-C2B10H10
  参考文献：
  名称：

  Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands

  摘要：

  Three mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands were synthesized and characterized by X-ray crystallography. The reactions of Ni(COD)(2)(COD=1,5-octadiene) with [(THF)(3)LiE2)C2B10H10Li(THF)](2) (E = S, Se) in THF in the presence of air in different ratios afforded the mono- and dinuclear nickel complexes of formulae Li(THF)(4)](2)[Ni(E2C2B10H10)(2)] (E=S, la; E=Se, 1b) and [Li(THF)(4)](2)[Ni-2(E(2)CZB(10)H(10))(3)] (E=S, 2a; E=Se, 2b). In 2a, two nickel atoms are connected by one chalcogen (eta(1),eta(2)-S2C2B10H10) bridging ligand with strong metal-metal interaction. Complex of formula (PPh3)(2)Ni(S2C2B10H10).0.5THF (3a) was also obtained from the reaction of (PPh3)(2)NiCl2 and [(THF)(3)LiS2C2B10H10Li(THF)](2). (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.05.001

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.12, 4.10, page 108 - 154
  作者：

  DOI：——

  日期：——
• A New Series of Organoboranes. IX. The Preparation and Some Reactions of Sulfur-Carborane Derivatives
  作者：H. D. Smith、C. O. Obenland、S. Papetti

  DOI：10.1021/ic50040a014

  日期：1966.6
• 1,2-Bis-substituted o-carborane complexes. II. Nickel(II) and cobalt(II) complexes derived from the ligand 1,2-bis(mercapto)-o-carborane
  作者：Hampton D. Smith、Martin Alvin Robinson、Stelvio Papetti

  DOI：10.1021/ic50051a035

  日期：1967.5