2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine | 1036023-55-8

• 英文名称: 2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine
• CAS: 1036023-55-8
• 化学式: C₁₂₀H₇₀N₁₆O₂Zn₂
• 分子量: 1898.76
• InChiKey: XMDIWKKMDVJOHY-KDSTWIIXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine 、 zinc diacetate 以 N,N-二甲基甲酰胺 为溶剂， 以91%的产率得到2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine zinc(II)
  参考文献：
  名称：

  Energy transfer in zinc porphyrin–phthalocyanine heterotrimer and heterononamer studied by fluorescence resonance energy transfer (FRET)

  摘要：

  Two or eight zinc triphenyl porphyrins were conjugated with Zn-phthalocyanine or H-2-phthalocyanine to form ZnPc-(ZnTPP)(2), ZnPc-(ZnTPP)(8), H2Pc-(ZnTPP)(2) and H2Pc-(ZnTPP)(8). Energy transfers from the porphyrin moiety to phthalocyanine part were quantitatively studied with the modality of fluorescence resonance energy transfer (FRET). By measuring the fluorescence increment from the phthalocyanine moiety and the decrease from porphyrin part under selective excitation at the B band of the porphyrin part in those conjugated compounds and their equimolar mixture of compositions, energy transfer efficiencies were estimated to be 90% for H2Pc-(ZnTPP)(8) and ZnPc-(ZnTPP)(8), and 60%, 30% for ZnPc-(ZnTPP)(2) and H2Pc-(ZnTPP)(2), respectively. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.07.010
• 作为产物：
  描述：

  4,5-bis[5-(4-phenoxy)-10,15,20-triphenyl pophyrin]-1,2-dicarbonitrile zinc(II) 、 subphthalocyanine 在 1,8-diazabicylo[5,4,0]undec-7-ene 作用下， 以 二甲基亚砜 为溶剂， 以6%的产率得到2,3-di-[5-(4-phenoxy)-10,15,20-triphenyl porphyrin zinc (II)] phthalocyanine
  参考文献：
  名称：

  Energy transfer in zinc porphyrin–phthalocyanine heterotrimer and heterononamer studied by fluorescence resonance energy transfer (FRET)

  摘要：

  Two or eight zinc triphenyl porphyrins were conjugated with Zn-phthalocyanine or H-2-phthalocyanine to form ZnPc-(ZnTPP)(2), ZnPc-(ZnTPP)(8), H2Pc-(ZnTPP)(2) and H2Pc-(ZnTPP)(8). Energy transfers from the porphyrin moiety to phthalocyanine part were quantitatively studied with the modality of fluorescence resonance energy transfer (FRET). By measuring the fluorescence increment from the phthalocyanine moiety and the decrease from porphyrin part under selective excitation at the B band of the porphyrin part in those conjugated compounds and their equimolar mixture of compositions, energy transfer efficiencies were estimated to be 90% for H2Pc-(ZnTPP)(8) and ZnPc-(ZnTPP)(8), and 60%, 30% for ZnPc-(ZnTPP)(2) and H2Pc-(ZnTPP)(2), respectively. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.07.010