[RuH(CO)(PPh3)2(4-picoline)2]BF4 | 221446-66-8

• 英文名称: [RuH(CO)(PPh3)2(4-picoline)2]BF4
• CAS: 221446-66-8
• 化学式: BF₄*C₄₉H₄₅N₂OP₂Ru
• 分子量: 927.731
• InChiKey: ZQWPBOSPTJWLCJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-甲基吡啶 、 RuH₂(CO)(PPh₃)₃ 、 tropylium tetrafluoroborate 以 四氢呋喃 为溶剂， 以62%的产率得到[RuH(CO)(PPh3)2(4-picoline)2]BF4
  参考文献：
  名称：

  New synthesis of [RuH(CO)(PPh3)2L2][BF4] [L2=2py, 2(4-Mepy) or bpy] and X-ray crystal structure of [RuH(CO)(PPh3)2(4-Mepy)2][BF4]

  摘要：

  The title compounds were prepared by reaction of RuH2(CO)(PPh3)(3) with [C7H7][BF4] in the presence of excess pyridine, 4-picoline or 2,2'-bipyridine. The compounds were characterized by IR, H-1 and P-31 NMR, and X-ray crystallography (for the 4-Mepy complex). The spectroscopic data as well as the results of the X-ray crystal structure show that the complexes contain trans-oriented phosphines and cis-pyridines. Details of the structural content and selected bond distances and angles are internally consistent. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00355-7