[(Me₂-Xyl-DAB)Pd(η³-6-methyloct-2-en-1-id)][SbF₆] | 1549535-80-9

• 英文名称: [(Me₂-Xyl-DAB)Pd(η³-6-methyloct-2-en-1-id)][SbF₆]
• 英文别名: [(2,3-dimethyl-1,4-bis(2,6-dimethylphenyl)diazabuta-1,3-diene)Pd(η³-6-methyloct-2-en-1-id)][SbF₆]
• CAS: 1549535-80-9
• 化学式: C₂₉H₃₉N₂Pd*F₆Sb
• 分子量: 757.802
• InChiKey: BTTZSIKCJUEYEL-YQLHJHTQSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver hexafluoroantimonate 、 chloromethyl(1,5-cyclooctadiene)palladium(II) 、 N,N'-bis(2,6-dimethylphenyl)butane-2,3-diimine 以 四氢呋喃 为溶剂， 反应 6.25h， 以26%的产率得到[(Me₂-Xyl-DAB)Pd(η³-6-methyloct-2-en-1-id)][SbF₆]
  参考文献：
  名称：

  Unexpected formation of [(Me2-Xyl-DAB)Pd(η3-6-methyloct-2-en-1-id)][SbF6] (Me2-Xyl-DAB = 2,3-dimethyl-1,4-bis(2,6-dimethylphenyl)-diazabuta-1,3-diene)

  摘要：

  Reaction of [(COD)Pd(Me)Cl] with Ag[SbF6] and 1.5 eq of the N<^>N Me-2-Xyl-DAB (2,3-dimethyl-N,N'-bis(2,6-dimethylphenyl)-diazabuta-1,3-dien) afforded the title complex [(Me-2-Xyl-DAB) Pd(eta(3)-6-methylcyclooct-2-en-1-id)][SbF6]. From a single crystal XRD study, H-1 NMR and MS it is clear, that the compound contains a cationic Pd(II) complex with a neutral diaza-butadiene chelate ligand and an anionic, thus allylic, eta(3)-6-methyl-cyclooct-2-en-1-id coligand. Presumably, the cationic complex has been formed by methylation of one of the olefin groups of the coordinated COD ligand. Details of this very interesting reaction were discussed in view of much related observations. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.07.071