1,2-diferrocenyl-2-trimethylsiloxyphosphaethene | 190968-55-9

• 英文名称: 1,2-diferrocenyl-2-trimethylsiloxyphosphaethene
• CAS: 190968-55-9；190968-59-3
• 化学式: C₂₄H₂₇Fe₂OPSi
• 分子量: 502.231
• InChiKey: NNSZCNMWGLYORZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,2-diferrocenyl-2-trimethylsiloxyphosphaethene 在 EtOH 、 n-BuLi 、 I₂ 作用下， 以 乙二醇二甲醚 、 正己烷 、 甲苯 为溶剂， 生成 1,2-diferrocenyl-1,2-diferrocenyldiphosphane
  参考文献：
  名称：

  Synthesis and reactivity of P-ferrocenylalkylidenephosphanes and related iminophosphanes and diphosphenes

  摘要：

  P-Ferrocenyl-substituted alkylidenephosphanes have been prepared and characterized spectroscopically. Their ready conversion to the corresponding acylphosphanes and 1,2-diacyldiphosphanes, as well as a new type of phosphirene synthesis are presented. The X-ray structure of the tetraferrocenyl-substituted diacyldiphosphane has been investigated. Furthermore, P-ferrocenyl iminophosphanes and their complexation behaviour are described. Diferrocenyldiphosphene, which is known to be unstable, has been stabilized by complexation; this has been confirmed by NMR-spectroscopy and X-ray structure analysis.

  DOI：

  10.1016/s0022-328x(96)06482-0
• 作为产物：
  描述：

  ferrocenoyl chloride 、 ferrocenylbis(trimethylsilyl)phosphane 以 甲苯 为溶剂， 以99%的产率得到1,2-diferrocenyl-2-trimethylsiloxyphosphaethene
  参考文献：
  名称：

  Synthesis and reactivity of P-ferrocenylalkylidenephosphanes and related iminophosphanes and diphosphenes

  摘要：

  P-Ferrocenyl-substituted alkylidenephosphanes have been prepared and characterized spectroscopically. Their ready conversion to the corresponding acylphosphanes and 1,2-diacyldiphosphanes, as well as a new type of phosphirene synthesis are presented. The X-ray structure of the tetraferrocenyl-substituted diacyldiphosphane has been investigated. Furthermore, P-ferrocenyl iminophosphanes and their complexation behaviour are described. Diferrocenyldiphosphene, which is known to be unstable, has been stabilized by complexation; this has been confirmed by NMR-spectroscopy and X-ray structure analysis.

  DOI：

  10.1016/s0022-328x(96)06482-0