[5-methyl-1,3-bis(anilinothiocarbonyl)phenyl-C(2),S,S']chloroplatinum(II) | 906461-80-1

• 英文名称: [5-methyl-1,3-bis(anilinothiocarbonyl)phenyl-C(2),S,S']chloroplatinum(II)
• CAS: 906461-80-1
• 化学式: C₂₁H₁₇ClN₂PtS₂
• 分子量: 592.044
• InChiKey: WSBGLSWPOIPPQQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [5-methyl-1,3-bis(anilinothiocarbonyl)phenyl-C(2),S,S']chloroplatinum(II) 、 二甲基亚砜 以 乙醇 、 二甲基亚砜 为溶剂， 以4%的产率得到
  参考文献：
  名称：

  Versatile bridging ability of secondary thioamide group for constructing metal cluster based on pincer complex

  摘要：

  The crystallization of the SCS pincer platinum complex with secondary thioamide groups, [4-methyl-2,6-bis(anilinothiocarbonyl)-kappa S-2,S'-phenyl-kappa C-1]chloroplatinum(II), spontaneously forms a trinuclear cluster complex accompanied by liberating HCl in DMSO/EtOH mixture. The crystal structure of the SNS pincer copper complex with secondary thioamide groups, [2,5-bis(benzylaminothiocarbonyl)-kappa S-2,S'-pyrrolyl-kappa N-1] chlorocopper(II), exhibits a dimer structure bearing the bridging thioamide group. The thioamide group acts as the bridging ligand of the multimetallic complexes in different anionic and neutral manners. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.11.028
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 5-methyl-1,3-bis(anilinothiocarbonyl)benzene 以 溶剂黄146 为溶剂， 以63%的产率得到[5-methyl-1,3-bis(anilinothiocarbonyl)phenyl-C(2),S,S']chloroplatinum(II)
  参考文献：
  名称：

  Preparation and Characterization of Luminescent SCS and NCN Pincer Platinum Complexes Derived from 3,5-Bis(anilinothiocarbonyl)toluene

  摘要：

  Starting from 5-methyl-1,3-bis(anilinothiocarbonyl)benzene (1), two types of luminescent pincer platinum complexes with kappa S-3, C, S and kappa N-3, C, N coordination modes were obtained. Reaction of 1 with K2PtCl4 afforded a pincer Pt(II) complex (3) with the kappa S-3, C, S coordination mode, whereas oxidative cyclization of 1 yielded 5-methyl-1,3-bis(benzothiazol-2-yl)benzene (2), which provided a pincer Pt(II) complex (4) with the kappa N-3, C, N coordination mode. Molecular structures and photochemical properties of the complexes have been examined. The decay lifetimes of the emission from the complexes were in the range 10(-5)- 10(-6) s, which were indicative of phosphorescent emission.

  DOI：

  10.1021/om060016j