OsH(OH)(CO)(P((t)Bu)2Me)2 | 249634-33-1

• 英文名称: OsH(OH)(CO)(P((t)Bu)2Me)2
• CAS: 249634-33-1
• 化学式: C₁₉H₄₄O₂OsP₂
• 分子量: 556.705
• InChiKey: FROGKGCSWYEXET-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  OsH(OH)(CO)(P((t)Bu)2Me)2 、 氢气 以 氘代苯 为溶剂， 生成 OsH2(H2)(CO)(P((t)Bu)2Me)2
  参考文献：
  名称：

  Characterization and structure of OsH(OH)(CO)(PtBu2Me)2

  摘要：

  A synthesis of the title compound by hydrolysis of OsH(C6H5)(CO)((PBu2Me)-Bu-t)(2) has the advantage that the product shows H-1 NMR spectra free of the influence of hydrogen bonding to water impurity. In the solid stale, the hydroxyl group interacts weakly with that of a neighbor. The Os-OH bond is rapidly split by H-2, to give H2O and Os(H)(2)(H-2)(CO)((PBu2Me)-Bu-t)(2). (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00146-1
• 作为产物：
  描述：

  OsH(phenyl)(CO)(P((t)Bu)2Me)2 、 水 以 氘代甲苯 为溶剂， 生成 OsH(OH)(CO)(P((t)Bu)2Me)2
  参考文献：
  名称：

  Characterization and structure of OsH(OH)(CO)(PtBu2Me)2

  摘要：

  A synthesis of the title compound by hydrolysis of OsH(C6H5)(CO)((PBu2Me)-Bu-t)(2) has the advantage that the product shows H-1 NMR spectra free of the influence of hydrogen bonding to water impurity. In the solid stale, the hydroxyl group interacts weakly with that of a neighbor. The Os-OH bond is rapidly split by H-2, to give H2O and Os(H)(2)(H-2)(CO)((PBu2Me)-Bu-t)(2). (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00146-1