[(Mn(II)(N.N'-bis(salicylidene)-1,3-diaminopropane))2PbCl2] | 400783-11-1

• 英文名称: [(Mn(II)(N.N'-bis(salicylidene)-1,3-diaminopropane))2PbCl2]
• CAS: 400783-11-1
• 化学式: C₃₄H₃₂Cl₂Cu₂N₄O₄Pb
• 分子量: 965.85
• InChiKey: BCICRCNMMFIBEG-FOWFEXJWSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-二亚水杨基-1,3-二氨基丙烷 在 aq. NH₃ 作用下， 以 1,4-二氧六环 、 乙醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 [(Mn(II)(N.N'-bis(salicylidene)-1,3-diaminopropane))2PbCl2]
  参考文献：
  名称：

  INVESTIGATIONS ON SOME HETERO-TRINUCLEAR COMPLEXES OF NICKEL(II) AND COPPER(II)

  摘要：

  Ni(II) and Cu(II) complexes of N,N'-bis(salicylidene-1,3-diaminopropane) were prepared and found to form linear and non-linear trinuclear complexes. Elemental analyses, IR spectroscopy, thermogravimetry and X-ray diffraction techniques applied to the complexes yielded valuable information about their moleculer structures. It was observed that mu -bridges in these trinuclear complexes form through the phenolic oxygens of the ligand or through anions present in the medium. In the presence of acetate, nitrate or nitrite, mu -bridges form between a pair of atoms resulting in linear trinuclear complexes. However, the presence of chloride or bromide results in mu -bridges involving the phenolic oxygens of N,N'-Bis(salicylidene)-1,3-diaminopropane.

  DOI：

  10.1081/sim-100107713