chloro(2,2'-azobispyridine)(2,2':6',2''-terpyridine)ruthenium(II) perchlorate | 879016-27-0

• 英文名称: chloro(2,2'-azobispyridine)(2,2':6',2''-terpyridine)ruthenium(II) perchlorate
• 英文别名: [Ru(apy)(tpy)Cl](ClO4)
• CAS: 879016-27-0
• 化学式: C₂₅H₁₉ClN₇Ru*ClO₄
• 分子量: 653.446
• InChiKey: JAUVHNVOBITLJK-CRBINSBKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  chloro(2,2'-azobispyridine)(2,2':6',2''-terpyridine)ruthenium(II) perchlorate 、 sodium perchlorate 、 水 在 AgNO₃ 作用下， 以 水 、 丙酮 为溶剂， 以76%的产率得到aqua(2,2'-azobispyridine)(2,2':6',2''-terpyridine)ruthenium(II) diperchlorate dihydrate
  参考文献：
  名称：

  Ruthenium polypyridyl complexes containing the bischelating ligand 2,2′-azobispyridine. Synthesis, characterization and crystal structures

  摘要：

  Three ruthenium polypyridyl compounds of structural formula [Ru(apy)(tpy)Ln-(ClO4)((2-n)) (apy = 2,2'-azobispyridine; tpy = 2,2':6',2"-terpyridine; L = Cl, H2O, CH3CN) (1a-c) were synthesized and crystallized. These complexes were fully characterized by means of 1D and 2D H-1 NMR spectroscopy, as well as mass spectrometry and elemental analysis. Although in theory two isomers are possible, i.e. the one in which the central N atom in tpy is trans to the azo N in apy and the one in which the former is trans to the pyridine N in apy, in all cases only the latter was observed. The molecular structures of the compounds were elucidated by single-crystal X-ray diffraction. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.05.017
• 作为产物：
  描述：

  (E)-二(吡啶-2-基)二氮烯 、 {Ru(2,2':6',2''-terpyridine)Cl3}*3H2O 、 sodium perchlorate 在 LiCl 、 Et₃N 作用下， 以 乙醇 、 水 为溶剂， 以47%的产率得到chloro(2,2'-azobispyridine)(2,2':6',2''-terpyridine)ruthenium(II) perchlorate
  参考文献：
  名称：

  Ruthenium polypyridyl complexes containing the bischelating ligand 2,2′-azobispyridine. Synthesis, characterization and crystal structures

  摘要：

  Three ruthenium polypyridyl compounds of structural formula [Ru(apy)(tpy)Ln-(ClO4)((2-n)) (apy = 2,2'-azobispyridine; tpy = 2,2':6',2"-terpyridine; L = Cl, H2O, CH3CN) (1a-c) were synthesized and crystallized. These complexes were fully characterized by means of 1D and 2D H-1 NMR spectroscopy, as well as mass spectrometry and elemental analysis. Although in theory two isomers are possible, i.e. the one in which the central N atom in tpy is trans to the azo N in apy and the one in which the former is trans to the pyridine N in apy, in all cases only the latter was observed. The molecular structures of the compounds were elucidated by single-crystal X-ray diffraction. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.05.017