3',5,7-trihydroxy-4'-methoxy-6-(tricarbonyl[(1'',2'',3'',4''-η)-2''-methoxy-1'',3''-cyclohexadien-5''α-yl]iron(0))flavanone | 252881-08-6

• 英文名称: 3',5,7-trihydroxy-4'-methoxy-6-(tricarbonyl[(1'',2'',3'',4''-η)-2''-methoxy-1'',3''-cyclohexadien-5''α-yl]iron(0))flavanone
• CAS: 252881-08-6
• 化学式: C₂₆H₂₂FeO₁₀
• 分子量: 550.302
• InChiKey: WZOURPDJBNIXJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tricarbonyl(η(5)-2-methoxycyclohexadienyl)iron hexafluorophosphate 、 (S)-2,3-dihydro-5,7-dihydroxy-2-(3-hydroxy-4-methoxyphenyl)-4-benzopyrone 在 三乙胺 作用下， 以 乙腈 为溶剂， 以15%的产率得到3',5,7-trihydroxy-4'-methoxy-6-(tricarbonyl[(1'',2'',3'',4''-η)-2''-methoxy-1'',3''-cyclohexadien-5''α-yl]iron(0))flavanone
  参考文献：
  名称：

  Attachment of IR-active organometallic probe groups to flavonoid inducers of nod gene expression

  摘要：

  Direct reaction of flavanones with electrophilic tricarbonyl[(1,2,3,4, 5-eta)cyclohexadienyliron(1+) complexes affords organometallic derivatives for use as probes of molecular recognition events during the induction of nodulation genes in Rhizobium leguminosarum. A more selective preparation method has been developed by deprotonation of the flavanone prior to the addition of the cyclohexadienyliron complex. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00398-8