[Cd2(phenylselenolate)2(bromide)2(tricyclohexylphosphine)2] | 1233407-25-4

• 英文名称: [Cd2(phenylselenolate)2(bromide)2(tricyclohexylphosphine)2]
• 英文别名: [Cd2(SePh)2Br2(PCy3)2]
• CAS: 1233407-25-4
• 化学式: C₄₈H₇₆Br₂Cd₂P₂Se₂
• 分子量: 1257.63
• InChiKey: ZYVNUBNZIMRJMO-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cadmium(II) bromide tetrahydrate 、 Cd(SePh)2 、 三环己基膦 以 甲醇 为溶剂， 以82%的产率得到[Cd2(phenylselenolate)2(bromide)2(tricyclohexylphosphine)2]
  参考文献：
  名称：

  Synthesis, structural characterization and growth features of some (Ph)Se–Cd cluster compounds (Ph = phenyl)

  摘要：

  Cd(SePh)(2), CdBr(2)center dot 4H(2)O/Cdl(2) and PCh(3) (Ph = phenyl; PCh(3) = tricyclohexylphosphine) react to give [(SePh)(2)Cd(2)Br(2)(PCh(3))(2)] (1), [(SePh)(2)Cd(2)I(2)(PCh(3))(2)] (2) and [(SePh)(7)Cd(4)Br(PCh(3))](n) (3)The new compounds are examples of Cd(II) clusters obtained starting from the cluster-forming reagents Cd(SePh)(2) and CdX(2) (X = Br, I) in the presence of variable amounts of PCh(3). While 1 and 2 are single, tetranuclear clusters, compound 3 attains polymeric adamantanoid cages linked through selenium bridges. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.02.023