trans-dichloro(dimethyl sulfoxide)(thiazole)platinum(II) | 187022-50-0

• 英文名称: trans-dichloro(dimethyl sulfoxide)(thiazole)platinum(II)
• CAS: 187022-50-0
• 化学式: C₅H₉Cl₂NOPtS₂
• 分子量: 429.251
• InChiKey: QRQKUMFQDNRVKL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  噻唑 、 dichlorobis(dimethyl sulfoxide)platinum(II) 以 二甲基亚砜 为溶剂， 以75%的产率得到trans-dichloro(dimethyl sulfoxide)(thiazole)platinum(II)
  参考文献：
  名称：

  The bonding of thiazoles to platinum(II) complexes. X-ray crystal structure of cis- and trans-[Pt(dimethyl sulfoxide)(thiazole)Cl2]

  摘要：

  The crystal structures of neutral cis- and trans-[Pt(dimethyl sulfoxide) (thiazole)Cl-2] have been determined by X-ray diffraction. The longer C4-C5 bond distance of the N-coordinated thiazole in both the square planar complexes, as compared to the free ligand, is interpreted in terms of a negative charge density transfer toward the antibonding orbital system of the thiazolic ring.

  DOI：

  10.1016/s0020-1693(96)05391-1