3-[2-(3,5-dimethylphenyl)prop-2-yl]-trimethylsilylcyclopentadienyl trimethyl titanium | 920281-57-8

• 英文名称: 3-[2-(3,5-dimethylphenyl)prop-2-yl]-trimethylsilylcyclopentadienyl trimethyl titanium
• 英文别名: [(3,5-Me2-Ph-CMe2-η5-C5H3SiMe3]TiMe3
• CAS: 920281-57-8
• 化学式: C₂₂H₃₆SiTi
• 分子量: 376.493
• InChiKey: TYQMLCZFMGBQJQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  3-[2-(3,5-dimethylphenyl)prop-2-yl]-trimethylsilylcyclopentadienyl trimethyl titanium 、 三苯碳四(五氟苯基)硼酸盐 以 further solvent(s) 为溶剂， 生成 [(η6-3,5-Me2-Ph-CMe2-η5-C5H3SiMe3)TiMe2][B(C6F5)4]
  参考文献：
  名称：

  Otten, Edwin; Batinas, Aurora A.; Meetsma, Auke, Journal of the American Chemical Society, 2009, vol. 131, p. 5298 - 5312

  摘要：

  DOI：
• 作为产物：
  描述：

  3-[2-(3,5-dimethylphenyl)prop-2-yl]-trimethylsilylcyclopentadienyl titanium trichloride 、 甲基氯化镁 以 四氢呋喃 、 乙醚 为溶剂， 以99%的产率得到3-[2-(3,5-dimethylphenyl)prop-2-yl]-trimethylsilylcyclopentadienyl trimethyl titanium
  参考文献：
  名称：

  Selective ethylene trimerization: A study into the mechanism and the reduction of PE formation

  摘要：

  In the present study, the titanium-catalyzed ethylene trimerization in general, and more specifically, the concomitant PE formation have been studied. The polymer formation is undesirable as it not only will lead to lower I-hexene yields, but it can cause reactor fouling under the applied conditions (30-80 degrees C, toluene solvent). It is, therefore, important to know which factors are involved in the formation of polymeric products and how their formation can be reduced or even prevented. The PE formation turns out to be catalyzed by at least two different species. A significant amount of PE is formed in the early stages of the reaction, caused by the presence of partly alkylated titanium species. The PE formation during later stages of the reaction is due to degraded catalyst species, which means that polymer formation is an inherent property of this catalyst system. The polymer output can be reduced largely by premixing Cp'TiCl3 and methyl aluminoxane (MAO) prior to injection into the reactor. It was also demonstrated that the type of MAO activator/impurity scavenger is of great importance. For a low yield of PE it is essential to use an MAO that does not contain and/or is not able to generate aluminum hydride species. In the end the best results with respect to both productivity and selectivity were obtained by starting from trimethyl titanium compounds. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.12.030