2,3,6,7-tetrakis[4-(boronatodiphenylphosphino)butylthio]tetrathiafulvalene | 1178859-27-2

• 英文名称: 2,3,6,7-tetrakis[4-(boronatodiphenylphosphino)butylthio]tetrathiafulvalene
• CAS: 1178859-27-2
• 化学式: C₇₀H₈₄B₄P₄S₈
• 分子量: 1349.1
• InChiKey: RIGSFNFQUKBRNG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2,3,6,7-tetrakis[4-(boronatodiphenylphosphino)butylthio]tetrathiafulvalene 在 三乙烯二胺 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以68%的产率得到4-[[2-[4,5-Bis(4-diphenylphosphanylbutylsulfanyl)-1,3-dithiol-2-ylidene]-5-(4-diphenylphosphanylbutylsulfanyl)-1,3-dithiol-4-yl]sulfanyl]butyl-diphenylphosphane
  参考文献：
  名称：

  Bimetallamacrocycles involving tetrakis(diphenylphosphinoalkylthio)tetrathiafulvalene

  摘要：

  Two novel tetrathiafulvalene (TTF) ligands, substituted by four diphenylphosphinoalkylthio groups, have been synthesized and characterized. Their redox properties, determined by cyclic voltammetry, have been compared with their precursors and discussed. The ability of these redox active ligands to react with two equivalent of cis-W(CO)(4)(C5H11N)(2) is presented. X-ray crystal structure of a bis 13-metallamacrocycle is reported together with its redox behaviour. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.006
• 作为产物：
  描述：

  (4-bromobutyl)diphenylphosphine-borane 、 2,3,6,7-四(2-氰乙基硫代)四硫富瓦烯 在 caesium carbonate 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 15.0h， 以68%的产率得到2,3,6,7-tetrakis[4-(boronatodiphenylphosphino)butylthio]tetrathiafulvalene
  参考文献：
  名称：

  Bimetallamacrocycles involving tetrakis(diphenylphosphinoalkylthio)tetrathiafulvalene

  摘要：

  Two novel tetrathiafulvalene (TTF) ligands, substituted by four diphenylphosphinoalkylthio groups, have been synthesized and characterized. Their redox properties, determined by cyclic voltammetry, have been compared with their precursors and discussed. The ability of these redox active ligands to react with two equivalent of cis-W(CO)(4)(C5H11N)(2) is presented. X-ray crystal structure of a bis 13-metallamacrocycle is reported together with its redox behaviour. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.006