decamethylferrocenium nitrate | 1037557-02-0

• 英文名称: decamethylferrocenium nitrate
• CAS: 1037557-02-0
• 化学式: C₂₀H₃₀Fe*NO₃
• 分子量: 388.31
• InChiKey: WURRRNMPIDGLLI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  decamethylferrocenium nitrate 、 sodium docusate 以 氯仿 、 水 为溶剂， 反应 0.17h， 以62%的产率得到
  参考文献：
  名称：

  Ferrocenium ionic liquids containing 3,4,5-tri(dodecyloxy)benzene sulfonate and bis(2-ethylhexyl)sulfosuccinate (AOT) anions

  摘要：

  The salts of the dodecyloctamethylferrocenium cation (1) and decamethylferrocenium cation (2) with the mesogenic anions of 3,4,5-tri(dodecyloxy)benzene sulfonate [(C12H25O)(3)C6H2SO3] and bis(2-ethylhexyl)sulfosuccinate (AOT) were prepared. The resulting materials, [1][(C12H25O)(3)C6H2SO3], [2] [(C12H25O)(3)C6H2SO3], and [1][AOT] were ionic liquids exhibiting glass transitions at -53, -41, and -51 degrees C, respectively, whereas [2][AOT] was a solid with a high melting point (T-m = 122 degrees C). The melting points and glass transition temperatures correlated with the flexibility of the substituents and the size of the constituent molecules. None of the salts exhibited liquid crystal phases. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.11.027
• 作为产物：
  描述：

  bis(pentamethylcyclopentadienyl)iron(II) 、 silver nitrate 以 丙酮 为溶剂， 以84%的产率得到decamethylferrocenium nitrate
  参考文献：
  名称：

  十甲基二茂铁鎓盐与全氟烷基磺酸盐和-羧酸盐阴离子的相变和热性质表现出无序性

  摘要：

  十甲基二茂铁鎓盐与全氟烷基磺酸根阴离子（C。ñF。2个ñ+1个所以第三名--; n  = 1、4和8）和全氟烷基羧酸根阴离子（C。ñF。2个ñ+1个一氧化碳2个--; n  = 1-4）用于研究阴离子对盐的热行为的影响。差示扫描量热法（DSC）测量表明，所有盐在固态下均表现出相变。具有八甲基二茂铁鎓阳离子或十甲基钴co鎓阳离子的盐表现出与相应的十甲基二茂铁鎓盐不同的相序。用结晶学方法研究了两种盐与相变有关的结构变化。[Fe（C 5 Me 5）2 ]（CF 3 SO 3）在-121.6°C时伴随着阳离子构象以不同比例排列为偏影和交错构象的顺序。在低温阶段，单位晶胞体积变大六倍，并且空间群从P mn2 1变为P 1。[Fe（C 5 Me 5）2 ]（C 3 F 7 CO 2）在-115°C时的相变不伴随晶胞或空间群（P 2 1 / c）。在低温相中，存在于高温相中的阴离子的释放或位移被抑制，这

  DOI：

  10.1016/j.jorganchem.2012.04.005

文献信息

• Decamethylferrocene Redox Chemistry and Gold Nanowire Electrodeposition at Salt Crystal|Electrode|Nonpolar Organic Solvent Contacts
  作者：John D. Watkins、Christopher E. Hotchen、John M. Mitchels、Frank Marken

  DOI：10.1021/om2006112

  日期：2012.4.9

  This report describes exploratory experimental findings for electrochemical processes in nonpolar solvents (hexane, toluene, and dichloroethane). Conventional 3 mm diameter glassy-carbon-disk electrodes are used in contact with a crystalline salt electrolyte (ammonium nitrate) immersed in nonpolar solvents. The insoluble salt is employed as a "surface thin film electrolyte", with humidity causing electrical connection from the working electrode to the SCE counter-reference electrode. The organic solvents are employed without intentionally added electrolyte. Humidity in the nonpolar solvents is shown to be essential for the processes to work. The oxidation of decamethylferrocene is demonstrated as a test organometallic redox system. The electrochemical reduction of Au(III) in toluene (solubilized with tetraoctylammonium bromide, TOABr) is employed to demonstrate and visualize the reaction zone around salt crystallworking electrode contact points. Gold nanowire bundle formation is observed, presumably due to an ordered interfacial surfactant microphase at saltlelectrode contact points. The triple phase boundary nature of these processes is discussed, and future applications are suggested.