1,2-bis(chlorophenylphosphanyl)-1,2-dicarba-closo-dodecaborane(12) | 210905-26-3

• 英文名称: 1,2-bis(chlorophenylphosphanyl)-1,2-dicarba-closo-dodecaborane(12)
• 英文别名: 1.2-(P(C6H5)Cl)2-1.2-C2B10H10；rac-1,2-bis(phenylchlorophosphino)-1,2-dicarba-closo-dodecaborane(12)；1,2-bis(phenylchlorophosphino)-1,2-dicarba-closo-dodecaborane(12)
• CAS: 210905-26-3
• 化学式: C₁₄H₂₀B₁₀Cl₂P₂
• 分子量: 429.276
• InChiKey: VECMWICIJKWGQU-HNRBIFIRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,2-bis(chlorophenylphosphanyl)-1,2-dicarba-closo-dodecaborane(12) 在 sulphur 作用下， 以 further solvent(s) 为溶剂， 以57%的产率得到1,2-bis(phenylthiophosphoryl)-1,2-dicarba-closo-dodecaborane(12)-dithiodiphosphinic acid
  参考文献：
  名称：

  The reaction of phenylchlorophosphino-substituted1,2-dicarba-closo-dodecaboranes(12) with elemental sulfur and molecular structures ofrac-1,2-bis(phenylchlorophosphino)-1,2-dicarba-closo-dodecaborane(12) and 1-phenylchlorothiophosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

  摘要：

  DOI：

  10.1016/s0277-5387(98)00330-1
• 作为产物：
  描述：

  1,2-dilithio-o-carborane 、 苯基二氯化磷 以 苯 为溶剂， 生成 1,2-bis(chlorophenylphosphanyl)-1,2-dicarba-closo-dodecaborane(12)
  参考文献：
  名称：

  Chemistry of Decaborane-Phosphorus Compounds. IV. Monomeric, Oligomeric, and Cyclic Phosphinocarboranes

  摘要：

  DOI：

  10.1021/ic50010a006

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.12, 4.10, page 108 - 154
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.12, 4.82, page 53 - 65
  作者：

  DOI：——

  日期：——
• Synthesis, molecular structure and reactivity of the first secondary carbaboranylbisphosphine 1,2-bis(phenylphosphino)-1,2-dicarba-closo-dodecaborane(12)
  作者：Viktor P. Balema、Maren Pink、Joachim Sieler、Evamarie Hey-Hawkins、Lothar Hennig

  DOI：10.1016/s0277-5387(97)00426-9

  日期：1998.5

  The reaction of a diastereomeric mixture of 1,2-bis(phenylchlorophosphino)-1,2-dicarba-closo-dodecaborane (12) (1) with LiAlH4, followed by hydrolysis with H2O, gives a 4:1 mixture of rac- and meso-1,2-bis(phenylphosphino)-1,2-dicarba-closo-dodecaborane(12) (2a, b) or 1-phenylphosphino-1,2-dicarba-closa-dodecaborane(12) (3), depending on the stoichiometry employed. A mixture of 2a, b reacts with sulfur in undecane at 190 degrees C or without solvent at 105-110 degrees C to give exclusively the cyclic anhydride of 1,2-bis(phenylthiophosphoryl)-1,2-dicarba-closo-dodecaboranyl(12)-dithiodiphosphinic acid (6). 2, 3 and 6 were characterised spectroscopically (H-1, P-31, B-11, C-13 NMR, IR, MS) and X-ray structure determinations were carried out on the racemic isomers 2a and 6. (C) 1998 Elsevier Science Ltd. All rights reserved.
• Carbaborane-Substituted 1,2,3-Triphospholanes and 1-Aza-2,5-diphospholane: New Synthetic Approaches
  作者：Anika Kreienbrink、Sarah Heinicke、Thi Thuy Duong Pham、René Frank、Peter Lönnecke、Evamarie Hey-Hawkins

  DOI：10.1002/chem.201302878

  日期：2014.1.27

  AbstractNew phosphorus‐containing, five‐membered P,P,P and P,N,P heterocycles were synthesized and fully characterized. The P,P,P heterocycles, 1,2,3‐triphospholanes, can be synthesized by two different facile pathways, whereas the P,N,P compound, a 1‐aza‐2,5‐diphospholane, can only be obtained with silylamine.
• Synthesis and molecular structure of (R,R\S,S)-[PdCl2{ {1,2-(PPhCl)2C2B10H10} }]
  作者：Viktor P Balema、Steffen Blaurock、Vitalij K Pecharsky、Evgeny G Rys、Evamarie Hey-Hawkins

  DOI：10.1016/s0277-5387(98)00183-1

  日期：1998.10

  The complex (R,R/S,S)-[PdCl21,2-(PPhCl)(2)C2B10H10}] (1) was prepared by the reaction of (R,R/S,S)-1,2-(PPhCl)(2)C2B10H10 with [(COD)PdCl2] (COD = cyclooctadiene) in CH2Cl2 solution and characterized by NMR spectroscopy (P-31, B-11, H-1) and X-ray structure determination (space group P-). Due to the crystallographic center of inversion, both enantiomeric isomers (R,R) and (S,S) are present in the unit cell. The Pd atom is coordinated in a square-planar fashion by two chloro ligands: and the 1,2-bis(phenylchlorophosphino)-1,2-dicarba-closo-dodecaborane (12) (C) 1998 Elsevier Science Ltd. All rights reserved.