| 1246560-84-8

• CAS: 1246560-84-8
• 化学式: C₆₀H₇₄AgGe₂*F₆Sb
• 分子量: 1284.04
• InChiKey: QZENAYAZTUWPHV-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 氯苯 为溶剂， 以30%的产率得到
  参考文献：
  名称：

  A Ditetrylyne as a π-Electron Donor: Synthesis and Characterization of [AgAr′GeGeAr′]⁺SbF₆⁻ and [Ag₂Ar′GeGe(F)Ar′]⁺SbF₆⁻ (Ar′ = C₆H₃-2,6(C₆H₃-2,6-Prⁱ₂)₂)

  摘要：

  The reaction of a digermyne Ar'GeGeAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pr-2(i))(2)) with AgSbF6 at -40 degrees C forms the complex (AgAr'GeGeAr')+SbF6-, which provides the first example of a heavier group 14 element alkyne analogue behaving as a pi donor to a transition metal. The cation (AgAr'GeGeAr')(+) is best described as a hybrid of a pi-complex and a sigma-metallacyclopropene structure.

  DOI：

  10.1021/ja1051236
• 作为产物：
  描述：

  silver hexafluoroantimonate 、 (Ge(C₆H₃)-2,6-(C₆H₃-2,6-ⁱPr)₂)₂ 以 氯苯 为溶剂， 以23%的产率得到
  参考文献：
  名称：

  A Ditetrylyne as a π-Electron Donor: Synthesis and Characterization of [AgAr′GeGeAr′]⁺SbF₆⁻ and [Ag₂Ar′GeGe(F)Ar′]⁺SbF₆⁻ (Ar′ = C₆H₃-2,6(C₆H₃-2,6-Prⁱ₂)₂)

  摘要：

  The reaction of a digermyne Ar'GeGeAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pr-2(i))(2)) with AgSbF6 at -40 degrees C forms the complex (AgAr'GeGeAr')+SbF6-, which provides the first example of a heavier group 14 element alkyne analogue behaving as a pi donor to a transition metal. The cation (AgAr'GeGeAr')(+) is best described as a hybrid of a pi-complex and a sigma-metallacyclopropene structure.

  DOI：

  10.1021/ja1051236