[Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)] | 202214-22-0

• 英文名称: [Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)]
• CAS: 202214-22-0
• 化学式: C₁₆H₂₀NRhS₂
• 分子量: 393.379
• InChiKey: MLGZGRFRXLGNKA-GHDUESPLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)] 在 acetone 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 生成 [Rh2(μ-N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)(CO)2]BF4
  参考文献：
  名称：

  Rhodium Dithiocarbamate Compounds as Metalloligands:  A Controlled Way for the Construction of Binuclear Complexes

  摘要：

  The preparation of N-methyl,N-phenyl-dithiocarbamate mononuclear rhodium(I) complexes is described, and their capability to act as metalloligands for the controlled construction of binuclear dithiocarbamate-bridged species of general formula [Rh-2{mu-S2CN(Me)(Ph)}(COD)L-2]BF4 is investigated. Although in the mononuclear complexes the dithiocarbamate group coordinates as an S,S'-chelate ligand, in the reported binuclear compounds this ligand shows a novel bridging eta(2),eta(2)(S,S') coordination mode. EHT calculations based on these binuclear complexes indicate the intermetallic symmetric mu-eta,(2) eta(2)(S,S') coordination to be the most stable situation.

  DOI：

  10.1021/ic971053t
• 作为产物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 methyl-phenyl-dithiocarbamic acid ; compound with triethylamine 以 二氯甲烷 为溶剂， 以90%的产率得到[Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)]
  参考文献：
  名称：

  Rhodium Dithiocarbamate Compounds as Metalloligands:  A Controlled Way for the Construction of Binuclear Complexes

  摘要：

  The preparation of N-methyl,N-phenyl-dithiocarbamate mononuclear rhodium(I) complexes is described, and their capability to act as metalloligands for the controlled construction of binuclear dithiocarbamate-bridged species of general formula [Rh-2{mu-S2CN(Me)(Ph)}(COD)L-2]BF4 is investigated. Although in the mononuclear complexes the dithiocarbamate group coordinates as an S,S'-chelate ligand, in the reported binuclear compounds this ligand shows a novel bridging eta(2),eta(2)(S,S') coordination mode. EHT calculations based on these binuclear complexes indicate the intermetallic symmetric mu-eta,(2) eta(2)(S,S') coordination to be the most stable situation.

  DOI：

  10.1021/ic971053t