| 237060-00-3

• CAS: 237060-00-3
• 化学式: C₄₂H₇₇NO₃P₂Ru
• 分子量: 807.096
• InChiKey: WGKIYGPULJBUQS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 苯乙炔 、 三环己基膦 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Preparation, Reaction, and Catalysis of the New Ruthenium Carbamato Complex Et₂NCO₂RuH(CO)(PCy₃)₂

  摘要：

  CO2 promoted the RuCl3. 3H(2)O-catalyzed dimerization of phenylacetylene (2) in the presence of PR3 (R = Bu, Cy) and Et2NH to afford 1,4-diphenyl-2-buten-3-yne (3). Et2NCO2RuH(CO)(PCy3)(2) (4) and (PhC=C)(2)Ru(CO)(PCy3)(2) (5) were isolated by the RuCl3. 3H(2)O/PCy3/Et2NH/CO2 and 4/2 reactions, respectively, and catalyzed the dimerization of 2 to afford 3 with the concomitant formation of a poly(phenylacetylene).

  DOI：

  10.1021/om990306i
• 作为产物：
  描述：

  水合三氯化钌 、 二氧化碳 、 二乙胺 、 三环己基膦 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Preparation, Reaction, and Catalysis of the New Ruthenium Carbamato Complex Et₂NCO₂RuH(CO)(PCy₃)₂

  摘要：

  CO2 promoted the RuCl3. 3H(2)O-catalyzed dimerization of phenylacetylene (2) in the presence of PR3 (R = Bu, Cy) and Et2NH to afford 1,4-diphenyl-2-buten-3-yne (3). Et2NCO2RuH(CO)(PCy3)(2) (4) and (PhC=C)(2)Ru(CO)(PCy3)(2) (5) were isolated by the RuCl3. 3H(2)O/PCy3/Et2NH/CO2 and 4/2 reactions, respectively, and catalyzed the dimerization of 2 to afford 3 with the concomitant formation of a poly(phenylacetylene).

  DOI：

  10.1021/om990306i