bis(μ-chloro)tetra-tert-butyldiindium(III) | 113088-74-7

• 英文名称: bis(μ-chloro)tetra-tert-butyldiindium(III)
• CAS: 113088-74-7
• 化学式: C₁₆H₃₆Cl₂In₂
• 分子量: 529.008
• InChiKey: PORGNSWOLFKPOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(μ-chloro)tetra-tert-butyldiindium(III) 在 n-BuLi 作用下， 以 乙醚 、 正己烷 、 正戊烷 为溶剂， 生成 bis(μ-ethoxo)tetra-tert-butyldiindium(III)
  参考文献：
  名称：

  Bradley, Donald C.; Frigo, Dario M.; Hursthouse, Michael B., Organometallics, 1988, vol. 7, # 5, p. 1112 - 1115

  摘要：

  DOI：

文献信息

• Synthesis and characterization of new monomeric dialkylindium amides
  作者：Kevin M. Simpson、Robert W. Gedridge、Kelvin T. Higa

  DOI：10.1016/0022-328x(93)83312-j

  日期：1993.8

  A series of organoindium amido compounds have been prepared for use as dopants in the organometallic vapor phase epitaxy (OMVPE) of II-VI semiconductor materials. Thus, reaction of tBu2InCl or iPr2InCl with the appropriate lithium or sodium dialkyiamide afforded compounds of the type R2InNR2' (where R = (t)Bu, (i)Pr, and R' = Me, (i)Pr, SiMe3). Similarly, reaction of the N-lithiated derivative of NCMe2(CH2)3CMe2 gave iPr2InNCMe2(CH)3CMe2. All of the compounds are monomeric liquids, except for the compound where R = (t)Bu, R' = Me, which is a dimeric solid. The compounds have been characterized by H-1 and C-13 NMR, IR, molecular weight determination, and elemental analysis. In addition, properties relevant to the OMVPE process such as volatility and photosensitivity are presented and evaluated.