1,3-dimesityl-4-octadecyl-4,5-dihydro-1H-imidazol-3-ium tetrafluoroborate | 953018-45-6

• 英文名称: 1,3-dimesityl-4-octadecyl-4,5-dihydro-1H-imidazol-3-ium tetrafluoroborate
• CAS: 953018-45-6
• 化学式: BF₄*C₃₉H₆₃N₂
• 分子量: 646.747
• InChiKey: KZRLJIJVZICLDG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Grubbs catalyst first generation 、 1,3-dimesityl-4-octadecyl-4,5-dihydro-1H-imidazol-3-ium tetrafluoroborate 、 细辛脑 在 potassium 2-methylbutan-2-olate 、 copper(l) chloride 作用下， 以 正己烷 、 二氯甲烷 为溶剂， 以40%的产率得到
  参考文献：
  名称：

  Catalytic surfactants for ring-opening metathesis polymerization and ring-closing metathesis in non-degassed micellar solutions

  摘要：

  Metathesis catalysts bearing long alkyl chains and analogous to Hoveyda's catalyst have been synthesized. Their surface-active properties have been characterized by formation of Langmuir films at the air-water interface. They have been dispersed in micelles formed in non-degassed water and been used in polymerization of a hydrophilic monomer. These surfactants are therefore the first inisurf molecules for metathesis polymerization that are air-stable. Their ability to catalyze ring-closing metathesis in water has also been evaluated. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2006.08.015