[Cu(o-(diphenylphosphino)benzaldehyde)((Ph2PC5H4)2Fe)][BF4] | 850799-42-7

• 英文名称: [Cu(o-(diphenylphosphino)benzaldehyde)((Ph2PC5H4)2Fe)][BF4]
• CAS: 850799-42-7
• 化学式: BF₄*C₅₃H₄₃CuFeOP₃
• 分子量: 995.043
• InChiKey: DOYOUSSECVDVOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1'-双(二苯基膦)二茂铁 、 [Cu(o-(diphenylphosphino)benzaldehyde)2(acetonitrile)][BF4] 以 四氢呋喃 为溶剂， 以56%的产率得到[Cu(o-(diphenylphosphino)benzaldehyde)((Ph2PC5H4)2Fe)][BF4]
  参考文献：
  名称：

  Syntheses, characterization and crystal structures of copper(I) o-(diphenylphosphino)benzaldehyde complexes

  摘要：

  The complexes [Cu(PCHO)(2)(NCMe)][BF4] (1) and [Cu(PCHO)(3)][BF4](2) have been prepared by treating [Cu(NCMe)(4)][BF4] with two and three equivalents of Ph2P(o-C6H4)C(=O)H (abbreviated as PCHO) at room temperature, respectively. The reaction of I and (Ph2PC5H4)(2)Fe (abbreviated as DPPF) affords [Cu(PCHO)(DPPF)][BF4] (3). The molecular structures of 1-3 have been determined by an X-ray diffraction study. The aldehyde groups in I are pendant, while one of the formyl groups in 2 is weakly coordinated to the copper ion through the oxygen atom. On the other hand, the copper atom in 3 is strongly chelated by both DPPF and PCHO ligands. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.12.049