(E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle(0)-1,5-cyclooctadiene | 1361408-36-7

• 英文名称: (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle(0)-1,5-cyclooctadiene
• CAS: 1361408-36-7
• 化学式: C₄₁H₄₉N₃Ni₂O₆S₃
• 分子量: 893.435
• InChiKey: FTYMZASZKXFAOH-HYRMLYRCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  一氧化碳 、 (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle(0)-1,5-cyclooctadiene 以 四氢呋喃 为溶剂， 生成 tetracarbonyl nickel
  参考文献：
  名称：

  Nickel(0) Complexes of Polyunsaturated Azamacrocyclic Ligands

  摘要：

  A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested.

  DOI：

  10.1021/om201271y
• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 (E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne 以 四氢呋喃 为溶剂， 以91%的产率得到(E,E)-1,6,11-tris(4-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8-diene-13-yne-dinickle(0)-1,5-cyclooctadiene
  参考文献：
  名称：

  Nickel(0) Complexes of Polyunsaturated Azamacrocyclic Ligands

  摘要：

  A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested.

  DOI：

  10.1021/om201271y