[PdCl2(S(piperidino)OMe)2] | 158564-36-4

• 英文名称: [PdCl2(S(piperidino)OMe)2]
• CAS: 158564-36-4
• 化学式: C₁₂H₂₆Cl₂N₂O₂PdS₂
• 分子量: 471.809
• InChiKey: BPKZJPWSAFOALA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 methyl piperidinosulfenate 以 甲苯 为溶剂， 以46%的产率得到[PdCl2(S(piperidino)OMe)2]
  参考文献：
  名称：

  Synthesis and vibrational spectra of new bis(alkoxysulfane)-dichloropalladium(II) complexes and X-ray structural analysis of [PdCl2{S(OPri)2}2]

  摘要：

  Reactions of L = (Pr(i)O)2S, (PrnO)2S, (MeO)(C4H8NO)S (C4H8NO = morpholino), (MeO) (C5H10N)S (C5H10N = piperidino) or (MeO)PhS with [PdCl2(NCPh)2] in toluene gave five complexes of type [PdCl2L2] (yields 40-79%). An X-ray structural analysis of the air-stable, monoclinic crystals of [PdCl2{S(OPe)2}2] showed the sulfur atoms to be cis-planar co-ordinated. The two co-ordinated dialkoxysulfane ligands are rotational isomers with differing SO torsional angles (+79 and 84-degrees for ligand 1, -106 and +82-degrees for 2). The S-0 bond lengths are in the range 1.586-1.611 angstrom. The infrared and Raman spectra of the five [PdCl2L2] complexes demonstrate that the rule of mutual exclusion is not obeyed, indicating a cis rather than a trans co-ordination in each case.

  DOI：

  10.1039/dt9940002509