[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)] | 910212-19-0

• 英文名称: [(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]
• 英文别名: (η5-C5H5)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)
• CAS: 910212-19-0
• 化学式: C₁₉H₂₀FeN₂O₂
• 分子量: 364.227
• InChiKey: VXZOASXJHDNLIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  cis-dichlorobis(dimethylsulfoxide)platinum(II) 、 [(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)] 以 甲醇 为溶剂， 以40%的产率得到rac-σPt[(η5-Cp)Fe(η5-C5H3-CH2N(methyl)-benzyl-4'-nitro)](chloride)(DMSO)
  参考文献：
  名称：

  Activation of the CH bond in [(η5-C5H5)Fe(η5-C5H4CH2N(CH3)CH2C6H4R-4)] induced by platinum (II): Crystal structure of σ-Pt[(η5-C5H5)Fe(η5-C5H3CH2N(CH3)CH2C6H4OCH3-4)]Cl(DMSO)

  摘要：

  Condensations of ferrocenylcarboxaldehyde (1) and p-methyl (2b) or p-chlorobenzylamines (2d) in methanol resulted in ferrocenylaldimines 3b, d which were reduced by lithium aluminum hydride to give 4b, d, respectively. Reductive methylations of 4b, d with aqueous formaldehyde, sodium cyanoborohydride and acetic acid afforded the tertiary ferrocenylamines 5b, d. Treatment of 5a-e [(eta(5)-C5H5)Fe(eta(5)-C5H4CH2N(CH3)CH2C6H4R-4)] (R = CH3O(a), CH3(b), H(c), Cl(d), NO2(e)) with cis-[Pt(DMSO)(2)Cl-2] in methanol produced predominately cycloplatinated complexes 6a-e sigma-Pt[(eta(5)-C5H5)Fe(eta(5)-C5H3CH2N(CH3)CH2C6H4-R-4)]Cl(DMSO) (R = same as before) in which the configurations consisted of RNRP and SNSP, In addition, the preferred activation of the C-H bond in the cyclopentadienyl ring rather than that in the phenyl ring was also observed. All compounds 3b-5b, 3d-5d, 6a-e were characterized by elemental analysis, IR and H-1 NMR. The structure of 6a was determined by X-ray single crystal diffraction. The possible mechanism for the formation of 6 was discussed. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.02.017
• 作为产物：
  描述：

  聚合甲醛 、 (η5-C5H5)Fe(η5-C5H4CH2NHCH2C6H4NO2-4) 在 sodium cyanoborohydride 、 acetic acid 作用下， 以 水 、 乙腈 为溶剂， 以85%的产率得到[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]
  参考文献：
  名称：

  Synthesis, characterization of [{(N-methyl-N-benzyl)amino}methyl]ferrocenes and their cyclopalladated complexes: Crystal structure of σ-Pd[(η5-C5H5)Fe(η5-C5H3CH2N(CH3)CH2C6H4NO2-4)]Cl(PPh3)

  摘要：

  Condensation of aminomethylferrocene (1) and substituted benzaldehydes resulted in aldimines 2a-c which followed by reduction with sodium borohydride to give 3a-c. N-methylation of 3a-c with HCHO/NaCNBH3/HOAc led to 4a-c. Treatment of 4a-c with sodium palladium tetrachloride in the presence of sodium acetate afforded cleanly cyclopalladated 5a-c in which configurations consisted of the RNRC, SNSC. The preferable activation Of C-Ferrocenyl-H bond over C-Phenyl-H bond was also observed. All compounds 2-5 were characterized by elemental analysis, IR and H-1 NMR. In addition, the molecular structure of 5c was confirmed by single crystal X-ray diffraction. The possible mechanism for the formation of 5 was also discussed. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.05.019